1355037-30-7

Basic information

• Product Name: 3,4,5-trihexylsulfanylphenylhydrazine
• CAS NO: 1355037-30-7
• Molecular Weight: 456.825
• Mol File: 1355037-30-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,4,5-trihexylsulfanylphenylhydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-trihexylsulfanylphenylhydrazine(1355037-30-7)
• EPA Substance Registry System: 3,4,5-trihexylsulfanylphenylhydrazine(1355037-30-7)

Safety Data

• Hazardous Substances Data: 1355037-30-7(Hazardous Substances Data)

Upstream product

• 22487-02-1 sodium n-hexylmercaptide 
• 138526-69-9 3,4,5-trifluoro-1-bromobenzene 
• 321984-01-4 1-bromo-3,4,5-trihexylsulfanylbenzene 
• 1374877-00-5 1,2-bis(tert-butoxycarbonyl)-1-(3,4,5-trihexylsulfanylphenyl)hydrazine 

Downstream Products

• 1355037-45-4 3,4,5-trihexylsulfanylbenzaldehyde 3,4,5-trihexylsulfanylphenylhydrazone 
• 1355037-29-4 1,3,5-tri-(3,4,5-trihexylsulfanylphenyl)-6-oxoverdazyl 
• 1355037-37-4 2,4,6-tri(3,4,5-trihexylsulfanylphenyl)-1,2,4,5-tetrazane-3-one 
• 1355037-41-0 3,4,5-trihexylsulfanylbenzaldehyde α-chloroformyl-3',4',5'-trihexylsulfanylphenylhydrazone 

Relevant articles and documents

Induction of columnar discotic behavior in verdazyl radicals with alkylsulfanyl substituents

Substitution of the 1,3,5-triphenyl-6-oxoverdazyl radical with n-alkylsulfanyl groups lead to derivatives 1[n], which exhibit a columnar rectangular phase (Colr) below 60 °C. Compounds 1[n] have a broad absorption band in the visible region with maxima at 540 and 610 nm and redox potentials E0/+1 1/2 = +0.99 V and E0/-1 1/2 =-0.45 V vs. SCE. Time-of-flight (TOF) investigation of 1[8] revealed hole mobility of μh = 1.52 × 10-3 cm2 V-1 s-1 in the columnar phase with an activation energy Ea = 0.06 ± 0.01 eV. Magnetization studies of 1[8] demonstrated nearly ideal paramagnetic behavior in both solid and fluid phases above 200 K and weak antiferromagnetic interactions at low temperatures. Verdazyl derivatives 1[n] were prepared in a sequence of reactions starting from 1-bromo-3,4,5-trifluorobenzene by alkylsulfanylation, followed by hydrazinylation, and finally 6-oxoverdazyl ring assembly using the Milcent method.