1355037-37-4Relevant articles and documents
Induction of columnar discotic behavior in verdazyl radicals with alkylsulfanyl substituents
Jankowiak, Aleksandra,Pociecha, Damian,Monobe, Hirosato,Szczytko, Jacek,Debska, Zaneta,Romanski, Jaroslaw,Kaszynski, Piotr
, p. 418 - 426 (2013/07/26)
Substitution of the 1,3,5-triphenyl-6-oxoverdazyl radical with n-alkylsulfanyl groups lead to derivatives 1[n], which exhibit a columnar rectangular phase (Colr) below 60 °C. Compounds 1[n] have a broad absorption band in the visible region with maxima at 540 and 610 nm and redox potentials E0/+1 1/2 = +0.99 V and E0/-1 1/2 =-0.45 V vs. SCE. Time-of-flight (TOF) investigation of 1[8] revealed hole mobility of μh = 1.52 × 10-3 cm2 V-1 s-1 in the columnar phase with an activation energy Ea = 0.06 ± 0.01 eV. Magnetization studies of 1[8] demonstrated nearly ideal paramagnetic behavior in both solid and fluid phases above 200 K and weak antiferromagnetic interactions at low temperatures. Verdazyl derivatives 1[n] were prepared in a sequence of reactions starting from 1-bromo-3,4,5-trifluorobenzene by alkylsulfanylation, followed by hydrazinylation, and finally 6-oxoverdazyl ring assembly using the Milcent method.