321984-02-5

Basic information

• Product Name: 3,4,5-trihexylsulfanylbenzaldehyde
• Synonyms: 3,4,5-trihexylsulfanylbenzaldehyde
• CAS NO: 321984-02-5
• Molecular Weight: 454.806
• Mol File: 321984-02-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,4,5-trihexylsulfanylbenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-trihexylsulfanylbenzaldehyde(321984-02-5)
• EPA Substance Registry System: 3,4,5-trihexylsulfanylbenzaldehyde(321984-02-5)

Safety Data

• Hazardous Substances Data: 321984-02-5(Hazardous Substances Data)

Upstream product

• 4394-85-8 4-morpholinecarboxaldehyde 
• 321984-01-4 1-bromo-3,4,5-trihexylsulfanylbenzene 
• 111-31-9 Hexanethiol 
• 138526-69-9 3,4,5-trifluoro-1-bromobenzene 
• 22487-02-1 sodium n-hexylmercaptide 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 1355037-29-4 1,3,5-tri-(3,4,5-trihexylsulfanylphenyl)-6-oxoverdazyl 
• 1355037-37-4 2,4,6-tri(3,4,5-trihexylsulfanylphenyl)-1,2,4,5-tetrazane-3-one 
• 1355037-41-0 3,4,5-trihexylsulfanylbenzaldehyde α-chloroformyl-3',4',5'-trihexylsulfanylphenylhydrazone 
• 1355037-45-4 3,4,5-trihexylsulfanylbenzaldehyde 3,4,5-trihexylsulfanylphenylhydrazone 
• 321984-04-7 (3,4,5-tris-hexylsulfanyl-benzyl)-phosphonic acid diethyl ester 

Relevant articles and documents

Induction of columnar discotic behavior in verdazyl radicals with alkylsulfanyl substituents

Substitution of the 1,3,5-triphenyl-6-oxoverdazyl radical with n-alkylsulfanyl groups lead to derivatives 1[n], which exhibit a columnar rectangular phase (Colr) below 60 °C. Compounds 1[n] have a broad absorption band in the visible region with maxima at 540 and 610 nm and redox potentials E0/+1 1/2 = +0.99 V and E0/-1 1/2 =-0.45 V vs. SCE. Time-of-flight (TOF) investigation of 1[8] revealed hole mobility of μh = 1.52 × 10-3 cm2 V-1 s-1 in the columnar phase with an activation energy Ea = 0.06 ± 0.01 eV. Magnetization studies of 1[8] demonstrated nearly ideal paramagnetic behavior in both solid and fluid phases above 200 K and weak antiferromagnetic interactions at low temperatures. Verdazyl derivatives 1[n] were prepared in a sequence of reactions starting from 1-bromo-3,4,5-trifluorobenzene by alkylsulfanylation, followed by hydrazinylation, and finally 6-oxoverdazyl ring assembly using the Milcent method.

Synthesis and properties of novel fluoroionophores for Ag+-optode sensing based on oligophenylenevinylenes

Novel hexylsulfanyl substituted oligophenylenevinylenes have been designed and synthesized as fluoroionophores which selectively detect Ag+ ions in membrane optode sensors. In addition, the 4-phenyl-ring oligomer-based optode sensor exhibits higher sensitivity than that of the 3-phenyl-ring counterpart. (C) 2000 Elsevier Science Ltd.