1355956-63-6Relevant articles and documents
General and practical one-pot synthesis of dihydrobenzosiloles from styrenes
Kuznetsov, Alexey,Gevorgyan, Vladimir
, p. 914 - 917 (2012/05/05)
A one-pot synthesis of dihydrobenzosiloles from styrenes has been developed. The reaction involves the nickel-catalyzed hydrosilylation of styrene with diphenylsilane, followed by the iridium-catalyzed dehydrogenative cyclization. This method is efficient for both electron-rich and -deficient styrenes and exhibits good functional group tolerance, as well as excellent regioselectivity. The forming dihydrobenzosiloles can be efficiently converted into valuable benzosiloles or 2-hydroxyphenethyl alcohols.