29265-81-4

Basic information

• Product Name: 1-CHLORO-3-(1-PHENYL-VINYL)-BENZENE
• Synonyms: 1-CHLORO-3-(1-PHENYL-VINYL)-BENZENE
• CAS NO: 29265-81-4
• Molecular Formula: C₁₄H₁₁Cl
• Molecular Weight: 214.69
• Mol File: 29265-81-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 315.1±21.0 °C(Predicted)
• Appearance: /
• Density: 1.107±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-CHLORO-3-(1-PHENYL-VINYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-CHLORO-3-(1-PHENYL-VINYL)-BENZENE(29265-81-4)
• EPA Substance Registry System: 1-CHLORO-3-(1-PHENYL-VINYL)-BENZENE(29265-81-4)

Safety Data

• Hazardous Substances Data: 29265-81-4(Hazardous Substances Data)

Usage

General Description

1-Chloro-3-(1-phenyl-vinyl)-benzene, also known as 1-phenyl-1-(3-chlorophenyl)ethene, is an organic compound with the chemical formula C14H11Cl. It is classified as a chlorinated aromatic hydrocarbon and is commonly used in the production of pharmaceuticals, dyes, and other organic chemicals. The compound is a colorless to light yellow liquid with a sweet, aromatic odor. It is also used as a building block in the synthesis of various chemicals and can be found in some industrial processes and products. 1-Chloro-3-(1-phenyl-vinyl)-benzene is considered to be potentially hazardous and is subject to strict regulations and safety measures to prevent environmental contamination and health risks.

Upstream product

• 62460-99-5 (E)-4-methyl-N′-(1-phenylethylidene)benzenesulfonohydrazide 
• 63503-60-6 3-chlorophenylboronic acid 
• 98-81-7 1-bromovinylbenzene 
• 99-02-5 3'-Chloroacetophenone 
• 107776-74-9 1-(3-chloro-phenyl)-1-phenyl-ethanol 
• 100-58-3 phenylmagnesium bromide 
• 63269-86-3 3-methyl-3-phenyl-3H-diazirine 
• 90006-76-1 3-methyl-3-phenyl-diaziridine 
• 14428-98-9 N-benzyl-N-(1-phenylethylidene)amine 
• 98-86-2 acetophenone 
• 1016-78-0 3-chlorobenzophenone 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 62926-87-8 1,1-Difluor-1-(m-chlorphenyl)-2-phenylethan 
• 59888-12-9 1-Chloro-3-(1,2-difluoro-1-phenyl-ethyl)-benzene 
• 1355956-63-6 C₂₆H₂₁ClSi 
• 1355956-46-5 C₂₆H₂₃ClSi 

Relevant articles and documents

Method for synthesizing alpha,beta-unsaturated selenium compound

The invention belongs to the field of organic selenium chemistry, and particularly relates to a method for synthesizing an alpha,beta-unsaturated selenium compound. The compound is synthesized by using an aryl boronic acid compound, elemental selenium and a diarylethene compound as reaction substrates. The method avoids toxic selenium-mercury reagents and toxic selenide reagents, conforms to the modern green development concept, and provides a green and economical method for synthesizing unsaturated selenium compounds in the future.

Photocatalytic, Phosphoranyl Radical-Mediated N-O Cleavage of Strained Cycloketone Oximes

A photoinduced, phosphoranyl radical-mediated protocol for the direct N-O cleavage of strained cycloketone oximes via a polar/SET crossover process was developed for the first time. This visible-light-driven direct N-O activation mode for oxime offers beneficial features such as streamlined synthetic process and versatile photochemical reactivities. Consequently, the alkenes and α-trifluoromethyl alkenes with varied electronic and structural features acted as competent radical receptors in this protocol, enabling facile accesses to a range of elongated cyano and/or gem-difluoroalkene-bearing compounds.

Olefin-assisted iron-catalyzed alkylation of aryl chlorides

A selective and operationally simple ironcatalyzed cross-coupling of aryl chlorides with alkylmagnesium halides has been developed. The reaction tolerates various functional groups and exhibits high chemoselectivity even in the presence of aryl bromides. Mechanistic studies indicate the essential role of the olefin substituent for substrate activation. Competing polymerization and reduction are effectively suppressed.