135877-95-1

Basic information

• Product Name: triphenylmethyl 2-bromo-3,5-dimethoxybenzyl ether
• Synonyms: triphenylmethyl 2-bromo-3,5-dimethoxybenzyl ether
• CAS NO: 135877-95-1
• Molecular Weight: 489.409
• Mol File: 135877-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: triphenylmethyl 2-bromo-3,5-dimethoxybenzyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: triphenylmethyl 2-bromo-3,5-dimethoxybenzyl ether(135877-95-1)
• EPA Substance Registry System: triphenylmethyl 2-bromo-3,5-dimethoxybenzyl ether(135877-95-1)

Safety Data

• Hazardous Substances Data: 135877-95-1(Hazardous Substances Data)

Upstream product

• 74726-76-4 2-bromo-3,5-dimethoxybenzyl alcohol 
• 76-83-5 trityl chloride 

Relevant articles and documents

C-Glycosides. 9. Stereospecific Synthesis of C-Glycosidic Spiroketal of the Papulacandins

The reaction of ortho-lithiated triphenylmethyl benzyl ether with perbenzylated D-gluconolactone 1 followed by cyclization by BF3*Et2O provides a new stereospecific synthesis of C-glycosidic spiroketals.The structure of the peracetylated derivative was determined by X-ray diffraction.This methodology is applied to the synthesis of the spiroketal unit of papulacandins.