136378-30-8

Basic information

• Product Name: Naphthalene, 2-[(4-methylphenyl)sulfinyl]-
• CAS NO: 136378-30-8
• Molecular Formula: C17H14OS
• Molecular Weight: 266.364
• Mol File: 136378-30-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Naphthalene, 2-[(4-methylphenyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 2-[(4-methylphenyl)sulfinyl]-(136378-30-8)
• EPA Substance Registry System: Naphthalene, 2-[(4-methylphenyl)sulfinyl]-(136378-30-8)

Safety Data

• Hazardous Substances Data: 136378-30-8(Hazardous Substances Data)

Upstream product

• 4294-57-9 para-methylphenylmagnesium bromide 
• 95323-21-0 methyl naphthalene-2-sulfinate 
• 5720-05-8 4-methylphenylboronic acid 
• 106-43-4 para-chlorotoluene 
• 35330-76-8 2-methanesulfinylnaphthalene 
• 106-38-7 para-bromotoluene 
• 624-31-7 4-tolyl iodide 
• 55085-95-5 allyl(2-naphthyl)sulfoxide 
• 70936-26-4 2-naphthalenesulfinyl chloride 

Downstream Products

• 49833-45-6 tert-butyl 4-methylphenyl sulfoxide 
• 1774-35-2 di(p-tolyl) sulfoxide 

Relevant articles and documents

Palladium-Catalyzed Sulfinylation of Aryl- And Alkenylborons with Sulfinate Esters

An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.

Aryl sulfoxides from aliyi sulfoxides via [2,3]-sigmatropic rearrangement and domino Pd-catalyzed generation/ arylation of sulfenate anions

(Figure presented) Allylic sulfoxides, via [2,3]-sigmatropic rearrangement and oxidative addition of the resulting allylic sulfonate esters to Pd(0), are found to be excellent precursors of sulfenate anions. This hitherto unknown reactivity is applied in a new Pd(0)-catalyzed domino sequence involving sulfonate anion generation followed by arylation to afford aryl sulfoxides.