35330-76-8Relevant articles and documents
2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of Dimensionality on Functionality
Chen, Wei,Ding, Huimin,Lang, Xianjun,Luo, Yi,Meng, Yi,Shi, Ji-Long,Sun, Junliang,Wang, Cheng,Zheng, Anmin
, p. 3624 - 3629 (2020)
The construction of 2D and 3D covalent organic frameworks (COFs) from functional moieties for desired properties has gained much attention. However, the influence of COFs dimensionality on their functionalities, which can further assist in COF design, has
Ligand Modification of Au25 Nanoclusters for Near-Infrared Photocatalytic Oxidative Functionalization
Cai, Baogui,Kang, Xi,Li, Yangfeng,Pei, Yong,Tang, Li,Wang, Shuxin,Xiong, Lin,Xuan, Jun,Yin, Zhengmao,Zhu, Manzhou
supporting information, p. 3787 - 3792 (2022/03/15)
The inorganic-organic interface between metal catalysts and their substrates greatly influences reaction processes, but few studies of this interface have been conducted for a detailed understanding of its structure. Herein, we describe the synthesis and structural determination of an arylthiolated Au25(F-Ph)18- nanocluster and characterize in detail the key roles of its ligands in photocatalyzed oxidative functionalization reactions. The most significant findings are that (i) interactions are established between ligands to avoid distortion of the geometric structure, limit the Jahn-Teller effect, and protect the nanocluster from oxidization and (ii) the low energy gap (HOMO-LUMO) of the synthetic clusters enables three types of photocatalytic oxidative functionalization reactions by near-infrared light (850 nm).
Synthesis method of sulfoxide compound
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Paragraph 0031-0033; 0101-0103, (2021/04/07)
The invention discloses a method for preparing sulfoxide derivatives with industrial application value through substituted diaryl (heterocyclic aryl) and aryl (heterocyclic aryl) alkyl sulfide compounds. Under electrochemical reaction conditions, diaryl (heterocyclic aryl) and aryl (heterocyclic aryl) alkyl sulfide compounds which are wide in source and easy to prepare and have structural diversity are used as raw materials, lithium perchlorate (LiClO4) is used as an electrolyte, acetonitrile (CH3CN) is used as a solvent, and oxygen is used as an oxidizing agent to prepare the diaryl (heterocyclic aryl) and aryl (heterocyclic aryl) alkyl sulfoxide derivatives. Compared with reported preparation methods of sulfoxide derivatives, the preparation method disclosed by the invention is green, environment-friendly, safe, energy-saving, wide in substrate application range, good in compatibility of product functional groups, easy in obtaining of raw materials and simple and convenient to operate.