35330-75-7Relevant articles and documents
Reactions of Vinylphosphonates. 3. One-Pot Synthesis of Dienes and Their Analogues from Vinylphosphonates, Aldehydes and Diethyl Phosphonates
Minami, Toru,Tokumasu, Shigehumi,Hirao, Ichiro
, p. 2139 - 2140 (1985)
Functionalized dienes and tetraenes were synthesized in 26-63percent yields by the one-pot reaction of the phosphoryl-stabilized carbanions, prepared from the Michael addition of diethyl lithiophosphonate to vinylphosphonates, with aromatic aldehydes.A similar reaction using phthalaldehyde gave 2-methylsulfonylnaphthalene (7) in 31percent yield via an intramolecular double Horner-Wittig reaction.
Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation
Liu, Kai-Jian,Wang, Zheng,Lu, Ling-Hui,Chen, Jin-Yang,Zeng, Fei,Lin, Ying-Wu,Cao, Zhong,Yu, Xianyong,He, Wei-Min
supporting information, p. 496 - 500 (2021/01/28)
A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction. This journal is
Method for synthesizing aryl alkyl sulfone compound by promoting oxidation of aryl alkyl thioether compound through visible light
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Paragraph 0049-0052; 0057-0060; 0072-0075, (2021/02/13)
The invention discloses a method for synthesizing an aryl alkyl sulfone compound by promoting oxidation of an aryl alkyl thioether compound through visible light. The method comprises the following steps of: performing one-pot reaction on an aryl alkyl thioether compound and sodium trifluoromethanesulfinate in a diethylene glycol dibutyl ether solution system under the conditions of oxygen-containing atmosphere and 385-390 nm purple light irradiation to generate the aryl alkyl sulfone compound. The method has the advantages of mild conditions, simple operation, environmental protection, easilyavailable raw materials, excellent compatibility of substrate functional groups, high reaction yield and the like.