1365840-82-9Relevant articles and documents
Formation of optically pure cyclic amines by intramolecular conjugate displacement
Cheng, Ping,Clive, Derrick L. J.
, p. 3348 - 3364 (2012/05/20)
Intramolecular conjugate displacement (ICD) has been applied to the Morita-Baylis-Hillman adducts formed from (5S)-5-(l-menthyloxy)-2(5H)-furanone and aldehydes that carry a protected β- or γ-amino group. DIBAL-H reduction of the resulting ICD products releases optically pure six- or seven-membered cyclic amines having a stereogenic center α to nitrogen.