1370524-10-9

Basic information

• Product Name: 10-benzyloxycarbonyl-2-fluoro-9,10-dihydroacridine
• Synonyms: 10-benzyloxycarbonyl-2-fluoro-9,10-dihydroacridine
• CAS NO: 1370524-10-9
• Molecular Weight: 333.362
• Mol File: 1370524-10-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 10-benzyloxycarbonyl-2-fluoro-9,10-dihydroacridine(CAS DataBase Reference)
• NIST Chemistry Reference: 10-benzyloxycarbonyl-2-fluoro-9,10-dihydroacridine(1370524-10-9)
• EPA Substance Registry System: 10-benzyloxycarbonyl-2-fluoro-9,10-dihydroacridine(1370524-10-9)

Safety Data

• Hazardous Substances Data: 1370524-10-9(Hazardous Substances Data)

Upstream product

• 118-91-2 ortho-chlorobenzoic acid 
• 371-40-4 4-fluoroaniline 
• 125579-04-6 2-fluoro-9,10-dihydroacridine 
• 501-53-1 benzyl chloroformate 
• 54-60-4 4'-fluorodiphenylamine-2-carboxylic acid 

Relevant articles and documents

Sulfonic acid-catalyzed autoxidative carbon-carbon coupling reaction under elevated partial pressure of oxygen

An aerobic organocatalytic oxidative C-C bond formation reaction of benzylic C-H bonds with various C-nucleophiles is described. The coupling reaction proceeds by simply stirring the substrates under elevated partial pressure of oxygen in the presence of a sulfonic acid catalyst at room temperature. Elevation of the pressure enables the reaction of a broad scope of nucleophile substrates otherwise showing poor reactivity at ambient pressure. The benzylic C-H bonds of xanthene, acridanes, isochromane and related heterocycles could be functionalized with nucleophiles including ketones, 1,3-dicarbonyl compounds and aldehydes. Electron-rich arenes could be utilized as nucleophiles at elevated temperatures. The reactions are believed to proceed via autoxidation of the benzylic C-H bonds to the hydroperoxides and subsequent nucleophilic substitution catalyzed by sulfonic acids. Copyright