137104-37-1

Basic information

• Product Name: 2-Propenoic acid, 2-(bromomethyl)-3-(4-nitrophenyl)-, methyl ester, (Z)-
• CAS NO: 137104-37-1
• Molecular Formula: C11H10BrNO4
• Molecular Weight: 300.109
• Mol File: 137104-37-1.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-(bromomethyl)-3-(4-nitrophenyl)-, methyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-(bromomethyl)-3-(4-nitrophenyl)-, methyl ester, (Z)-(137104-37-1)
• EPA Substance Registry System: 2-Propenoic acid, 2-(bromomethyl)-3-(4-nitrophenyl)-, methyl ester, (Z)-(137104-37-1)

Safety Data

• Hazardous Substances Data: 137104-37-1(Hazardous Substances Data)

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 114106-93-3 methyl 2-[hydroxy(4-nitrophenyl)methyl]prop-2-enoate 

Downstream Products

• 1010833-04-1 methyl (Z)-3-(4-nitrophenyl)-2-(thiocyanomethyl)propenoate 
• 1010833-17-6 (5Z)-2-amino-5,6-dihydro-[5-(4-nitrobenzylidene)]-1,3-thiazin-4-one 
• 1361200-76-1 methyl 2-[(S)-{[(R)-1-(4-methoxyphenyl)ethyl]amino}(4-nitrophenyl)methyl]acrylate 
• 1361200-78-3 methyl 2-[(R)-{[(R)-1-(4-methoxyphenyl)ethyl]amino}(4-nitrophenyl)methyl]acrylate 
• 1361200-77-2 methyl 2-[(S)-{[(S)-1-(4-methoxyphenyl)ethyl]amino}(4-nitrophenyl)methyl]acrylate 
• 1361200-75-0 methyl 2-[(R)-{[(S)-1-(4-methoxyphenyl)ethyl]amino}(4-nitrophenyl)methyl]acrylate 
• 1361201-06-0 methyl (R)-2-{[(tert-butoxycarbonyl)amino](4-nitrophenyl)methyl}acrylate 
• 1361201-07-1 methyl (S)-2-{[(tert-butoxycarbonyl)amino](4-nitrophenyl)methyl}acrylate 
• 40277-76-7 methyl (E)-2-methyl-3-(4-nitrophenyl)acrylate 
• 84782-92-3 methyl 2-(4-nitrobenzyl)acrylate 
• 1367876-29-6 [(Z)-2-methoxycarbonyl-3-(4-nitrophenyl)-2-propenyl]triphenylphosphonium bromide 

Relevant articles and documents

Simple access to 2-methylalk-2-enoates and insect pheromones by zinc-promoted reduction of Baylis-Hillman-derived allylic bromides

(E)-2-Methylacrylates are prepared in good yield and high stereoselectivity by zinc-promoted reduction of 2-(bromomethyl)alkenoates derived from Baylis-Hillman adducts. Synthesis of the male ant pheromone (E)-2,4-dimethyl-2- hexenoic acid was performed using this simple methodology. (E)-2-Methylacrylates are easily prepared by zinc-promoted reduction of 2-(bromomethyl)alkenoates derived from Baylis-Hillman adducts. Synthesis of the male ant pheromone (E)-2,4-dimethyl-2-hexenoic acid was performed using this simple methodology.

New allyldithiocarbimates: Synthesis, Structure and Antifungal Activity against Phakopsora pachyrhizi and Hemileia vastatrix

Twelve tetraphenylphosphonium allyldithiocarbimates were synthesized and fully characterized by high-resolution electrospray ionization mass spectrometry (HR-ESI-MS), infrared and nuclear magnetic resonance (NMR) spectroscopies. The spectroscopic data ind

Design, synthesis and evaluation of 3-arylidene azetidin-2-ones as potential antifungal agents against Alternaria solani Sorauer

A new concise and facile method was explored to synthesize a collection of new 3-arylidene azetidin-2-ones, which could be regarded as the derivatives of the hybrid scaffold of bioactive natural cinnamamide and heterocycle azetidi-2-one. The structures of

Formal [3+2] annulation involving allylic bromides and thioureas. synthesis of 2-iminothiazolidines through a base-catalyzed intramolecular anti-Michael addition

A simple and efficient protocol was developed for the synthesis of 2-iminothiazolidines through a base-mediated [3+2] annulation involving substituted thioureas and allylic bromides bearing electron-withdrawing groups. This domino process consists of nucleophilic displacement, followed by intramolecular anti-Michael addition of the preformed allylic isothiourea under mild conditions to give the thiazolidine core.