84782-92-3

Basic information

• Product Name: methyl 2-(4-nitrobenzyl)acrylate
• Synonyms: methyl 2-(4-nitrobenzyl)acrylate
• CAS NO: 84782-92-3
• Molecular Weight: 221.213
• Mol File: 84782-92-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl 2-(4-nitrobenzyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-nitrobenzyl)acrylate(84782-92-3)
• EPA Substance Registry System: methyl 2-(4-nitrobenzyl)acrylate(84782-92-3)

Safety Data

• Hazardous Substances Data: 84782-92-3(Hazardous Substances Data)

Upstream product

• 84782-87-6 3-(4-Nitro-benzyl)-4-oxo-tetrahydro-thiophene-3-carboxylic acid methyl ester 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 56075-39-9 1-(methylsulfonyl)-2-(4-nitrophenyl)diazene 
• 126234-89-7 2-<(4-methylphenylsulfonyl)methyl>propenoic acid methyl ester 
• 771477-95-3 methyl 2-(bromomethyl)-3-(4-nitrophenyl)acrylate 
• 137104-37-1 methyl (Z)-2-(bromomethyl)-3-(4-nitrophenyl)-2-propenoate 
• 114106-93-3 methyl 2-[hydroxy(4-nitrophenyl)methyl]prop-2-enoate 
• 555-16-8 4-nitrobenzaldehdye 
• 1367876-29-6 [(Z)-2-methoxycarbonyl-3-(4-nitrophenyl)-2-propenyl]triphenylphosphonium bromide 
• 636-98-6 p-nitrobenzene iodide 
• 80-62-6 methacrylic acid methyl ester 

Relevant articles and documents

Ester-directed orthogonal dual C-H activation and: Ortho aryl C-H alkenylation via distal weak coordination

An unprecedented orthogonal cross-coupling between aromatic C(sp2) and aliphatic olefinic C(sp2) carbons of two same molecules via dual C-H bond activation in an intermolecular fashion has been developed using a distal ester-directing group. This new coupling reaction led to the synthesis of the highly functionalized 1,3-diaryl molecular architecture in very good yields and with high chemo- and regioselectivities. In addition, using ester as the distal directing group, ortho C-H olefination of α-methyl aryl acrylates and cinnamic esters with various alkenes has been achieved in very good yields and with a wide range of substrate scope. This journal is

Microwave-assisted synthesis of the (E)-α-methylalkenoate framework from multifunctionalized allylic phosphonium salts

A convenient and general microwave-assisted method for the synthesis of stereochemically defined α-methylalkenoic acids and esters from allylic phosphonium salts in a basic aqueous medium is described. A selective preparation of acids or esters was dependent on the base (NaOH or NaHCO 3) employed in the reaction and could be achieved with good to excellent yields under mild conditions in the absence of hydrides and reducing agents.

Methyl 4-Oxothiolane-3-carboxylate and Methyl 2-Methyl-4-oxothiolane-3-carboxylate Anions as Synthetic Equivalents of α-Acrylate and α-Crotonate Anions. Formal Synthesis of Integerrinecic Acid

The base-promoted fragmentation of the C-alkylation products (6a-h) and (8a-e) of methyl 4-oxothiolane-3-carboxylate (4) and methyl 2-methyl-4-oxothiolane-3-carboxylate (5) gave good yields of the α-substituted acrylates (7a-h) and α-substituted crotonate