137170-74-2

Basic information

• Product Name: trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene
• Synonyms: trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene
• CAS NO: 137170-74-2
• Molecular Weight: 302.437
• Mol File: 137170-74-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene(CAS DataBase Reference)
• NIST Chemistry Reference: trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene(137170-74-2)
• EPA Substance Registry System: trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene(137170-74-2)

Safety Data

• Hazardous Substances Data: 137170-74-2(Hazardous Substances Data)

Upstream product

• 103698-35-7 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane 
• 828-51-3 1-Adamantanecarboxylic acid 
• 963-16-6 (E)-1,2-bis(phenylsulfonyl)ethylene 
• 281-23-2 adamantane 
• 5535-48-8 PVS 
• 80859-83-2 1-benzene 

Relevant articles and documents

Copper-Catalyzed Intermolecular Functionalization of Unactivated C(sp3)-H Bonds and Aliphatic Carboxylic Acids

Intermolecular functionalization of C(sp3)-H bonds and aliphatic carboxylic acids enables the efficient synthesis of high value-added organic compounds from readily available starting materials. Although methods involving hydrogen atom transfer have been developed for such functionalization, these methods either work for only activated C(sp3)-H bonds or bring in a narrow set of functional groups. Here we describe a Cu-catalyzed process for the diverse functionalization of both unactivated C(sp3)-H bonds and aliphatic carboxylic acids. The process is enabled by the trapping of alkyl radicals generated through hydrogen atom abstraction by arylsulfonyl-based SOMO-philes, which introduces a large array of C, N, S, Se, and halide-based functional groups. The chemoselectivity can be switched from C-H functionalization to decarboxylative functionalization by matching the bond dissociation energy of the hydrogen atom transfer reagent with that of the target C-H or O-H bond.

Reductive Addition of Alkyl Radical to Phenyl Vinyl Sulfone

Radicals generated from (diacyloxyiodo)benzene readily added to phenyl vinyl sulfone to give 2-alkylethyl phenyl sulfone in the presence of a hydrogen donor such as 1,4-cyclohexadiene, 1,3-dioxolane, or triethylsilane.Among these donors, 1,4-cyclohexadien

SOME FURTHER NOVEL TRANSFORMATIONS OF GEMINAL (PYRIDINE-2-THIYL) PHENYLSULPHONES

Geminal (pyridine-2-thiyl) phenylsulphones, obtained by decarboxylative radical addition of O-acyl derivatives of N-hydroxy-2-thiopyridone onto phenyl vinyl sulphone, undergo a wide variety of further transformations when subjected to sodium telluride or to organoaluminum reagents.