1372784-13-8

Basic information

• Product Name: (E)-methyl 3-{2-(p-tolylsulfinylmethyl)phenyl}acrylate
• Synonyms: (E)-methyl 3-{2-(p-tolylsulfinylmethyl)phenyl}acrylate
• CAS NO: 1372784-13-8
• Molecular Weight: 314.405
• Mol File: 1372784-13-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-methyl 3-{2-(p-tolylsulfinylmethyl)phenyl}acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 3-{2-(p-tolylsulfinylmethyl)phenyl}acrylate(1372784-13-8)
• EPA Substance Registry System: (E)-methyl 3-{2-(p-tolylsulfinylmethyl)phenyl}acrylate(1372784-13-8)

Safety Data

• Hazardous Substances Data: 1372784-13-8(Hazardous Substances Data)

Upstream product

• 10381-70-1 benzyl 4-methylphenyl sulfoxide 
• 292638-85-8 acrylic acid methyl ester 
• 1512844-40-4 6-(p-tolylsulfanylmethyl)-benzene-1,2,3,4,5-d₅ 
• 1372783-78-2 6-(p-tolylthiomethyl)benzene-1,2,3,4,5-d₅ 
• 71258-22-5 benzyl bromide 
• 106-45-6 para-thiocresol 
• 100-39-0 benzyl bromide 
• 5023-60-9 1-benzylsulfanyl-4-methyl-benzene 
• 1372783-84-0 (E)-methyl 3-{2-(p-tolylthiomethyl)phenyl}acrylate 

Downstream Products

• 1372784-14-9 3-[2-(toluene-4-sulfonylmethyl)phenyl]acrylic acid methyl ester 
• 52753-91-0 (E)-methyl 3-(2-formylphenyl)acrylate 
• 216572-78-0 3-(2-hydroxymethylphenyl)acrylic acid methyl ester 

Relevant articles and documents

Palladium(II)-catalyzed ortho -olefination of arenes applying sulfoxides as remote directing groups

A novel palladium-catalyzed ortho-C(sp2)-H olefination protocol has been developed by the use of sulfoxide as the directing group. Importantly, relatively remote coordination can be accessed to achieve the ortho olefination of benzyl, 2-arylethyl, and 3-arylpropenyl sulfoxide substrates, and the olefinated sulfoxide can be easily transformed to other functionalities.