13735-82-5

Basic information

• Product Name: Silane, triphenyl[(1-phenylethenyl)oxy]-
• CAS NO: 13735-82-5
• Molecular Formula: C26H22OSi
• Molecular Weight: 378.546
• Mol File: 13735-82-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, triphenyl[(1-phenylethenyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, triphenyl[(1-phenylethenyl)oxy]-(13735-82-5)
• EPA Substance Registry System: Silane, triphenyl[(1-phenylethenyl)oxy]-(13735-82-5)

Safety Data

• Hazardous Substances Data: 13735-82-5(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 789-25-3 HSiPh₃ 
• 15812-05-2 1-Triphenylsilyl-2-phenyl-aethanon-⁽²⁾ 
• 1171-49-9 benzoyl-triphenyl-silane 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 53638-20-3 1-Phenyl-2-triphenylsilanyloxy-ethanone 

Relevant articles and documents

Base-free dehydrogenative coupling of enolizable carbonyl compounds with silanes

A dehydrogenative coupling between enolizable carbonyl compounds and equimolar amounts of triorganosilanes catalyzed by a tethered ruthenium complex with a Ru-S bond is reported. The complex is assumed to fulfill a dual role by activating the Si-H bond to release a silicon electrophile and by abstracting an α-proton from the intermediate silylcarboxonium ion, only liberating dihydrogen as the sole byproduct. Reaction rates are exceedingly high at room temperature with very low loadings of the ruthenium catalyst.