13750-34-0

Basic information

• Product Name: N--p-toluolsulfonamid
• Synonyms: N--p-toluolsulfonamid
• CAS NO: 13750-34-0
• Molecular Weight: 267.312
• Mol File: 13750-34-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N--p-toluolsulfonamid(CAS DataBase Reference)
• NIST Chemistry Reference: N--p-toluolsulfonamid(13750-34-0)
• EPA Substance Registry System: N--p-toluolsulfonamid(13750-34-0)

Safety Data

• Hazardous Substances Data: 13750-34-0(Hazardous Substances Data)

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 27703-15-7 N,N-dimethyl-N'-(toluene-4-sulfonyl)-carbamimidoyl chloride 
• 13839-37-7 N-<(Dimethylamino)hydrazinomethylen>-p-toluolsulfonamid 

Downstream Products

• 84274-84-0 N--p-toluolsulfonamid 
• 24762-04-7 2-Diazo-3-oxo-butyric acid methyl ester 
• 84274-87-3 N--4-methoxybenzolsulfonamid 
• 84274-88-4 N--p-toluolsulfonamid 
• 108-59-8 malonic acid dimethyl ester 
• 84274-95-3 1-1,N¹-Dimethyl-N²-(p-tosyl)amidino>-5--1,2,3-triazol 

Relevant articles and documents

Synthesis and Reactivity of N',N'-Disubstituted N-arenesulfonamides

The synthesis of the amidino azides 3a-k mentioned in the title can be performed by direct chloride/azide exchange of the correspondingly substituted chlorides 1 or by nitrosation of the corresponding hydrazine derivatives 2.The azides 3 show no tendency, to isomerize to the valence tautomeric 5-amino-1-(arylsulfonyl)tetrazoles 4. - The azides 3 react with triphenylphosphane under nitrogen evolution to give the iminophosphoranes 5, while with methylene-active compounds the corresponding diazo compounds and the guanidines 6 are formed.The amidino azides add smoothly to the ynamines 7 to furnish the triazoles 8 which, depending on the substituents, isomerize partly or completely to yield the diazoamidines 9.