1375488-03-1

Basic information

• Product Name: N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-2-iodoaniline
• Synonyms: N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-2-iodoaniline
• CAS NO: 1375488-03-1
• Molecular Weight: 548.423
• Mol File: 1375488-03-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-2-iodoaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-2-iodoaniline(1375488-03-1)
• EPA Substance Registry System: N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-2-iodoaniline(1375488-03-1)

Safety Data

• Hazardous Substances Data: 1375488-03-1(Hazardous Substances Data)

Upstream product

• 1375488-01-9 9-benzyl-1,4-dimethoxy-9H-carbazole-3-carbaldehyde 
• 615-43-0 2-iodophenylamine 
• 1375488-02-0 (9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methanol 
• 1375487-99-2 1-bromo-4-hydroxy-9H-carbazole-3-carbaldehyde 
• 1375487-97-0 4-hydroxy-9H-carbazole-3-carbaldehyde 
• 1375488-00-8 9-benzyl-(4-benzyloxy)-1-bromo-9H-carbazole-3-carbaldehyde 

Downstream Products

• 1375488-05-3 1-(12-benzyl-7,13-dimethoxy-6H,12H-5,12-diazaindeno[1,2-b]phenanthren-5-yl)-ethanone 
• 827340-35-2 12-benzyl-12H-5,12-diazaindeno[1,2-b]phenanthrene-7,13-dione 
• 1375488-04-2 N-[(9-benzyl-1,4-dimethoxy-9H-carbazol-3-yl)methyl]-N-(2-iodophenyl)acetamide 

Relevant articles and documents

Unexpected observations during the total synthesis of calothrixin B-sodium methoxide as a source of hydride

During the total synthesis of calothrixin B, various novel and unexpected results were noticed such as cleavage of C-N bond in imine using sodium cyanoborohydride, sodium methoxide as a hydride source for reduction, deformylation in the presence of bromine, and deacylation using ceric ammonium nitrate (CAN). A detailed mechanism has been proposed for the unexpected results and a few of them are generalized. Temperature dependent NMR studies have been carried out for confirmation of the structure of one of the intermediates in the synthetic sequence.