1375931-09-1Relevant articles and documents
Ruthenium-catalyzed ortho-C-H halogenations of benzamides
Wang, Lianhui,Ackermann, Lutz
, p. 1083 - 1085 (2014/01/17)
[Ru3(CO)12] and AgO2C(1-Ad) enabled the first ruthenium-catalyzed intermolecular halogenations of arenes via C-H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were ach
High-yielding, versatile, and practical [Rh(III)Cp*]-catalyzed ortho bromination and iodination of arenes
Schroeder, Nils,Wencel-Delord, Joanna,Glorius, Frank
, p. 8298 - 8301 (2012/06/29)
We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.