138528-82-2

Basic information

• Product Name: N-benzoylisoquinolinium triflate
• Synonyms: N-benzoylisoquinolinium triflate
• CAS NO: 138528-82-2
• Molecular Weight: 383.348
• Mol File: 138528-82-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzoylisoquinolinium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoylisoquinolinium triflate(138528-82-2)
• EPA Substance Registry System: N-benzoylisoquinolinium triflate(138528-82-2)

Safety Data

• Hazardous Substances Data: 138528-82-2(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 61206-56-2 N-benzoylisoquinolinium chloride 
• 119-65-3 isoquinoline 
• 98-88-4 benzoyl chloride 

Downstream Products

• 119-65-3 isoquinoline 
• 65-85-0 benzoic acid 
• 50624-29-8 N-benzoyl-1,2-dihydroisoquinoline 
• 93-97-0 benzoic acid anhydride 
• 61456-83-5 N-benzoyl-1-methyl-1,2-dihydroisoquinoline 
• 844-25-7 2-benzoyl-1-cyano-1,2-dihydroisoquinoline 
• 1468-28-6 4-benzoylmorpholine 
• 93-58-3 benzoic acid methyl ester 
• 138528-83-3 isoquinolinium trifluoromethanesulfonate 

Relevant articles and documents

Reissert Compound Studies. LXIV. Reissert Compound and Other Products From an Isolated N-Benzoylisoquinolinium Triflate Salt

In the presence of trimethylsilyl trifluoromethanesulfonate, a methylene chloride solution of isoquinoline and benzoyl chloride gave N-benzoylisoquinolinium triflate (3) and N-H-isoquinolinium triflate (4).Depending on the reaction conditions, reaction of 3 may occur on the isoquinoline ring yielding a Reissert compound and 1,2-dihydroisoquinoline species.Otherwise, reactions transpire on the carbonyl of 3 to give an amide, an ester, and an anhydride.