50624-29-8

Basic information

• Product Name: Isoquinoline, 2-benzoyl-1,2-dihydro-
• CAS NO: 50624-29-8
• Molecular Formula: C16H13NO
• Molecular Weight: 235.285
• Mol File: 50624-29-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Isoquinoline, 2-benzoyl-1,2-dihydro-(CAS DataBase Reference)
• NIST Chemistry Reference: Isoquinoline, 2-benzoyl-1,2-dihydro-(50624-29-8)
• EPA Substance Registry System: Isoquinoline, 2-benzoyl-1,2-dihydro-(50624-29-8)

Safety Data

• Hazardous Substances Data: 50624-29-8(Hazardous Substances Data)

Upstream product

• 143360-42-3 2-{[(Bis-trimethylsilanyl-methyl)-amino]-methyl}-benzoic acid methyl ester 
• 125951-14-6 2-{[(E)-Bis-trimethylsilanyl-methylimino]-methyl}-benzoic acid methyl ester 
• 143360-43-4 N-(Bis-trimethylsilanyl-methyl)-N-(2-formyl-benzyl)-benzamide 
• 138528-82-2 N-benzoylisoquinolinium triflate 

Relevant articles and documents

Fluoride Ion Mediated Peterson Alkenation of N-amido Derivatives with Carbonyl Compounds: A Short General Route to Enamides and 1,2-Dihydroisoquinolines

A straighforward general access to diversely substituted acyclic or cyclic enamides and dienamides is accomplished by using a fluoride induced Peterson olefination of carbonyl compounds and enolizable amides derived from C,C-bis(trimethylsilyl)methylamine

Reissert Compound Studies. LXIV. Reissert Compound and Other Products From an Isolated N-Benzoylisoquinolinium Triflate Salt

In the presence of trimethylsilyl trifluoromethanesulfonate, a methylene chloride solution of isoquinoline and benzoyl chloride gave N-benzoylisoquinolinium triflate (3) and N-H-isoquinolinium triflate (4).Depending on the reaction conditions, reaction of 3 may occur on the isoquinoline ring yielding a Reissert compound and 1,2-dihydroisoquinoline species.Otherwise, reactions transpire on the carbonyl of 3 to give an amide, an ester, and an anhydride.