139313-40-9

Basic information

• Product Name: 1-Butanone, 3-hydroxy-2-methyl-1-phenyl-
• CAS NO: 139313-40-9
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 139313-40-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1-Butanone, 3-hydroxy-2-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanone, 3-hydroxy-2-methyl-1-phenyl-(139313-40-9)
• EPA Substance Registry System: 1-Butanone, 3-hydroxy-2-methyl-1-phenyl-(139313-40-9)

Safety Data

• Hazardous Substances Data: 139313-40-9(Hazardous Substances Data)

Upstream product

• 6668-24-2 2-methyl-1-phenyl-1,3-butanedione 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 75-07-0 acetaldehyde 
• 585564-38-1 2-methyl-1-phenyl-1,3-butanediol 
• 93-55-0 1-phenyl-propan-1-one 
• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 

Downstream Products

• 63553-65-1 (1SR,2RS,3RS)-2-methyl-1-phenylbutane-1,3-diol 
• 848413-10-5 (2RS,3S)-3-hydroxy-2-methyl-1-phenylbutan-1-one 
• 63553-65-1 (1RS,2RS,3RS)-2-methyl-1-phenylbutane-1,3-diol 
• 19847-64-4 2-methyl-1-phenylbut-2-en-1-one 
• 139313-41-0 3-acetoxy-2-methylbutyrophenone 
• 431-03-8 dimethylglyoxal 

Relevant articles and documents

A chemo-enzymatic route to diastereoisomers of 2-methyl-1-phenyl-1,3-butanediol: the dual role of microorganisms

Diastereoisomers (1S,2R,3S)-, (1R,2R,3S)-, (1R,2S,3S)- and (1S,2S,3S)-2-methyl-1-phenyl-1,3-butanediols were prepared by simple and convenient strategies using two different chemo-enzymatic approaches for the reduction of racemic 2-methyl-1-phenyl-1,3-but

Synthesis of (+)-conagenin

An efficient total synthesis of (+)-conagenin was achieved. The right fragment of conagenin, α-methylserine containing a quaternary stereocenter attached to nitrogen, was synthesized using allyl cyanate-to-isocyanate rearrangement. The left fragment, 2,4-

Rare Earth Metal Complexes as Water-Tolerant Lewis Acid Catalysts in Organic Synthesis

Rare earth metal triflates are stable in aqueous media and can act as Lewis acid catalysts in several carbon-carbon bond forming reactions. This article describes some of these reactions; aldol and Mannich-type reactions in aqueous solution, and Friedel-Crafts acylations and Fries rearrangement in organic solvents. The reactions proceeded smoothly in the presence of a catalytic amount of the triflate under mild conditions. Moreover, the catalysts could be recovered after the reactions were completed and could be reused.