1395062-13-1

Basic information

• Product Name: S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate
• Synonyms: S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate
• CAS NO: 1395062-13-1
• Molecular Weight: 521.367
• Mol File: 1395062-13-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate(1395062-13-1)
• EPA Substance Registry System: S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate(1395062-13-1)

Safety Data

• Hazardous Substances Data: 1395062-13-1(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 78031-08-0 [(bromodifluoromethyl)sulfanyl]benzene 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 488-23-3 1,2,3,4-Tetramethylbenzene 

Downstream Products

• 1422736-32-0 2-bromo-3-(difluoromethoxy)cyclohex-2-enone 
• 1422736-31-9 3-(difluoromethoxy)-2-methylcyclohex-2-en-1-one 
• 1422736-30-8 3-(difluoromethoxy)cyclohex-2-en-1-one 
• 1422736-29-5 2-benzyl-3-(difluoromethoxy)cyclopent-2-en-1-one 
• 1422736-38-6 2-benzyl-3-(difluoromethoxy)-5-methylcyclohex-2-enone 
• 1422736-37-5 2-bromo-3-(difluoromethoxy)-5-methylcyclohex-2-enone 
• 1422736-36-4 3-(difluoromethoxy)-5-methylcyclohex-2-en-1-one 
• 1422736-35-3 2-benzyl-3-(difluoromethoxy)-5,5-dimethylcyclohex-2-enone 
• 1422736-34-2 2-bromo-3-(difluoromethoxy)-5,5-dimethylcyclohex-2-enone 
• 82477-45-0 3-(difluoromethoxy)-5,5-dimethylcyclohex-2-en-1-one 
• 1422736-33-1 2-benzyl-3-(difluoromethoxy)cyclohex-2-en-1-one 

Relevant articles and documents

Efficient synthesis of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts for electrophilic bromodifluoromethylating reagents

A series of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts 1 were readily synthesized by treatment of corresponding (bromodifluoromethyl) arylsulfoxides 2 and substituted benzenes 3 with triflic anhydride in moderate to good yields. The unsymmetrical sulfonium salts 1 with different aryl groups having electron-donating or electron-withdrawing substituents can be nicely constructed depending on the choice of 2 and 3. Bromodifluoromethylation of alkynes was evaluated by using the selected diarylsulfonium salts 1 to provide the desired bromodifluoromethylated alkynes in moderate to good yields.