14064-93-8

Basic information

• Product Name: Benzene, 1-methoxy-4-nitro-2-phenoxy-
• CAS NO: 14064-93-8
• Molecular Formula: C13H11NO4
• Molecular Weight: 245.235
• Mol File: 14064-93-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-nitro-2-phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-nitro-2-phenoxy-(14064-93-8)
• EPA Substance Registry System: Benzene, 1-methoxy-4-nitro-2-phenoxy-(14064-93-8)

Safety Data

• Hazardous Substances Data: 14064-93-8(Hazardous Substances Data)

Upstream product

• 60433-63-8 5-nitro-2-phenoxyphenol 
• 51230-16-1 2-methoxy-4-nitro-1-phenoxy-benzene 
• 77337-82-7 1-bromo-2-methoxy-4-nitrobenzene 
• 5847-59-6 2-bromo-4-nitrophenol 
• 52427-05-1 2-bromo-5-nitrophenol 
• 108-86-1 bromobenzene 
• 1695-04-1 2-methoxyphenyl phenyl ether 
• 7697-37-2 nitric acid 
• 64-19-7 acetic acid 
• 186581-53-3 diazomethane 
• 70995-08-3 Phenyl-(5-nitro-2-hydroxy-phenyl)-aether 
• 5197-28-4 2-bromo-4-nitroanisole 
• 100-67-4 potassium phenolate 

Downstream Products

• 1695-04-1 2-methoxyphenyl phenyl ether 
• 158430-70-7 4-acetamino-5-nitro-2-phenyloxyanisole 
• 158430-73-0 4-amino-5-nitro-2-phenyloxyanisole 
• 14064-98-3 acetic acid-(4-methoxy-3-phenoxy-anilide) 
• 17419-02-2 4-methoxy-3-phenoxy-aniline 
• 70995-08-3 Phenyl-(5-nitro-2-hydroxy-phenyl)-aether 

Relevant articles and documents

The Smiles Rearrangement of 2-Aryloxy-5-nitrophenoxides. Attempted Routes to Benzoxirens and Tribenzotrioxonins

Formation of dibenzo-p-dioxins by the pyrolysis of 2-halogenophenoxides does not appear to involve intermediate benzoxirens.Thermal self-condensation to potassium 2-bromo-5-nitrophenoxide (1b) gave a mixture of 2,7- and 2,8-dinitrobenzo-p-dioxins (6d) and (6e).The mechanism of formation of the 2,8-isomer (6e) is shown to involve Smiles rearrangement of potassium 2-(2-bromo-5-nitrophenoxy)-5-nitrophenoxide (9a).Further examples of Smiles rearrangements of 2-aryloxy-5-nitrophenoxides and an attempted synthesis of the tribenzotrioxonin derivatives (16) are described.