140696-24-8

Basic information

• Product Name: Cyclopropanemethanol, a-methyl-2-phenyl-
• CAS NO: 140696-24-8
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 140696-24-8.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Cyclopropanemethanol, a-methyl-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanemethanol, a-methyl-2-phenyl-(140696-24-8)
• EPA Substance Registry System: Cyclopropanemethanol, a-methyl-2-phenyl-(140696-24-8)

Safety Data

• Hazardous Substances Data: 140696-24-8(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 34271-31-3 trans-2-phenylcyclopropanecarbaldehyde 
• 593-71-5 Chloroiodomethane 
• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 74087-85-7 3,3-dimethyldioxirane 
• 1588-56-3 trans-2-phenyl-1-ethylcyclopropane 
• 1896-62-4 (E)-benzalacetone 
• 14371-10-9 (E)-3-phenylpropenal 
• 676-58-4 methylmagnesium chloride 
• 74-95-3 1,1-dibromomethane 
• 104974-60-9 rac-(Z)-4-phenylbut-3-en-2-ol 
• 75-11-6 diiodomethane 
• 186581-53-3 diazomethane 
• 122-57-6 1-Phenylbut-1-en-3-one 

Downstream Products

• 1745-16-0 5-phenylpent-2-ene 
• 79929-88-7 trans-5-phenyl-2-heptene 
• 3909-96-4 (1E,3E)-1-phenyl-1,3-pentadiene 
• 126525-29-9 N-((E)-1-Phenyl-pent-3-enyl)-acrylamide 
• 126525-28-8 N-((E)-1-Phenyl-pent-3-enyl)-acetamide 
• 75851-76-2 1-phenylpent-3-en-1-ol 
• 75851-76-2 (Z)-1-phenyl-3-penten-1-ol 
• 75851-77-3 (E)-1-phenyl-3-penten-1-ol 
• 58193-48-9 1-phenyl-1-hydroxy-pentane-4-one 
• 583-05-1 1-phenylpentane-1,4-dione 
• 79929-86-5 cis-1-(1-acetoxyethyl)-2-phenylcyclopropane 

Relevant articles and documents

Indium triflate catalyzed rearrangement of aryl-substituted cyclopropyl carbinols to 1,4-disubstituted 1,3-butadienes

Aryl-substituted cyclopropyl carbinol derivatives undergo a facile stereoselective rearrangement catalyzed by In(OTf)3 in dichloromethane under sonication to produce the substituted conjugated all-trans-butadienes. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

CYCLOPROPANATION PROCESS

A method for the preparation of cyclopropyl carbinols by cyclopropanation of unsaturated alcoholates, utilising a reagent system selected from (A) magnesium metal and dibromomethane, and (B) dibromomethane and a tertiary Grignard reagent, the reaction being carried out in the presence of an ether solvent. The process is useful, for example, for the preparation of ingredients for the flavour and fragrance industry.

Preparation of aryl-substituted E-homoallylic bromides from cyclopropylcarbinol and PBr3

An expeditious synthesis of aryl substituted E-homoallylic bromides has been accomplished by the cleavage of cyclopropylcarbinols with phosphorus tribromide. Copyright Taylor & Francis Group, LLC.