141869-55-8

Basic information

• Product Name: ethyl α,α-bis(methylthio)phenylacetate
• Synonyms: ethyl α,α-bis(methylthio)phenylacetate
• CAS NO: 141869-55-8
• Molecular Weight: 256.39
• Mol File: 141869-55-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl α,α-bis(methylthio)phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl α,α-bis(methylthio)phenylacetate(141869-55-8)
• EPA Substance Registry System: ethyl α,α-bis(methylthio)phenylacetate(141869-55-8)

Safety Data

• Hazardous Substances Data: 141869-55-8(Hazardous Substances Data)

Upstream product

• 1521187-12-1 ethyl methylsulfinylphenylacetate 
• 75280-06-7 ethyl α-(methylthio)phenylacetate 
• 2882-19-1 ethyl 2-phenyl-2-bromoacetate 
• 40167-20-2 N-(methylthio)phthalimide 
• 17097-90-4 2-phenylmalonic acid monoethyl ester 
• 2949-92-0 methanethiosulfonic acid S-methyl ester 
• 101-97-3 Ethyl 2-phenylethanoate 

Relevant articles and documents

An easy formation of dithioacetals on alumina-KF under microwave irradiation. Synthesis of new potential antiviral phosphonates

The preparation of dithioacetals by the reaction of methylene compounds with S-methyl methanesulfonothioate on Al2O3-KF is described. Microwave irradiation without solvent provides a powerful activation. Potential antiviral phosphona

New Decarboxylation, De-ethoxycarbonylation and Desulfonylation, followed by Sulfenylation of some Half-Esters of Malonic Acids and α-Sulfonylmalonic Esters

The sulfenylation of some half-esters of malonic acids and some α-sulfonylmalonic esters with several sulfenylating reagents was investigated.Evidence was provided that in the case of the half-esters, in which NaH-dimethyl sulfoxide was employed, the formation of α,α-disulfenylated carboxylic esters may occur by two different reaction sequences, initiated either by dianion formation or decarboxylation.It is shown that, in the case of the α-sulfonylmalonic esters, in which diazabicyclooctane in refluxing toluene was employed, two competitive reactions may take place: de-ethoxycarbonylation or desulfonylation, both followed by sulfenylation.