1422188-69-9

Basic information

• Product Name: C₃₈H₄₅F₆N₃Si
• CAS NO: 1422188-69-9
• Molecular Weight: 685.871
• Mol File: 1422188-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₈H₄₅F₆N₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₄₅F₆N₃Si(1422188-69-9)
• EPA Substance Registry System: C₃₈H₄₅F₆N₃Si(1422188-69-9)

Safety Data

• Hazardous Substances Data: 1422188-69-9(Hazardous Substances Data)

Upstream product

• 907590-97-0 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline 
• 2002-95-1 N-(hexafluoroisopropylidene)aniline 

Relevant articles and documents

Metal free and selective activation of one C-F bond in a bound CF 3 group

The first metal free selective C-F bond activation of a CF3 group was observed with N-heterocyclic silylenes [PhC(NtBu)2SiCl] (1) and [CH{(CCH2)(CMe)(2,6-iPr2C6H 3N)2}Si] (2) with PhNC(CF3)2. The reaction proceeds in a 1:1 molar ratio to yield the mono C-F bond activated products 3 and 4 with each containing a CF2 group. Both the reactions proceed through an unprecedented selective activation of one of the C-F bonds rather than forming the [1+2] cycloaddition product containing the three-membered SiNC rings.