2002-95-1Relevant articles and documents
Formylation of fluoroalkyl imines through visible-light-enabled H-atom transfer catalysis: Access to fluorinated α-amino aldehydes
Yang, Sen,Zhu, Shuangyu,Lu, Dengfu,Gong, Yuefa
supporting information, p. 2019 - 2024 (2019/04/10)
A visible-light-enabled catalytic formylation of fluoroalkyl imines is developed. With readily accessible starting materials and organocatalysts, this method provides a general approach to masked fluoroalkyl amino aldehydes. A synergistic catalytic effect
High-pressure 19F NMR study of the degenerate isomerization of hexafluoroacetone anils. Evidence for the existence of two different inversion transition states
Swaddle, Thomas W.,Doine, Hideo,Kinrade, Stephen D.,Sera, Akira,Asano, Tsutomu,Okada, Toshio
, p. 2378 - 2382 (2007/10/02)
Solvent, temperature, and pressure effects on the rate of the degenerate isomerization of hexafluoroacetone anils were studied by 19F NMR. The results unequivocally demonstrated that the mechanism is not rotation about the carbon-nitrogen bond