85290-62-6Relevant articles and documents
REDUCTIVE DEFLUORINATION OF HEXAFLUOROACETONE ANIL
Zeifman, Yu. V.
, p. 186 - 188 (2007/10/02)
Hexafluoroacetone anil smoothly adds methyllithium at the C=N bond but undergoes reductive defluorination upon the action of Grignard reagents or metallic zinc to give 2-phenylaminopentafluoropropylene.
BIS(1-TRIFLUOROMETHYL-2,2,2-TRIFLUOROETHOXY)TRIPHENYLPHOSPHORANE. A NEW ROUTE TO TRIFLUOROMETHYLATED HETEROCYCLES
Kubota, Toshio,Yamamoto, Kazuhiro,Tanaka, Tatsuo
, p. 167 - 168 (2007/10/02)
Bis(1-trifluoromethyl-2,2,2-trifluoroethoxy)triphenylphosphorane(1) readily reacted with anilines to form N-hexafluoroisopropylated products (2).By the dehydrofluorination of 2,2-arylamino-1,1,3,3,3-pentafluoropropenes(3) were obtained.Furthermore, when a