14222-98-1Relevant articles and documents
Tris(5-aryl-1,3,4-oxadiazolyl)benzotrithiophenes – Discotic Liquid Crystals with Enormous Mesophase Ranges
Tober, Natalie,Winter, Johannes,Jochem, Matthias,Lehmann, Matthias,Detert, Heiner
, p. 798 - 809 (2021/02/01)
C3-symmetrical, alkoxyphenyl substituted 2,5,8-(tris-1,3,4-oxadiazol-2-yl)benzo [1,2-b; 3,4-b′; 5,6-b′′]trithiophenes (OXD-BTT) are synthesized via threefold Huisgen-reaction. A broad variation of alkoxy substitution pattern and chain lengths is reported. The thermal behavior was investigated via differential scanning calorimetry (DSC), polarized optical microscopy (POM) and thermogravimetry (TGA). Optical properties were studied via UV-Vis and fluorescence spectroscopy. Structural information of the LC phases was gained from X-ray diffraction on oriented fibers. OXD-BTT provide enormous phase widths (ΔT≥289 K) with clearing points close to thermal decomposition. Most of the derivatives exhibit two different mesophases, the lower phase with a rectangular 3D-structure and a hexagonal 2D-lattice at higher temperature. The variation of the chain length allows a tuning of melting and clearing points. OXD-BTT emit blue light with fluorescence quantum yields up to 30 % in good solvents. The emission is very sensitive to aggregation, thus, in poor solvents the emission intensity decreases, and red shift of maxima occurs.
π-Conjugated Microporous Polymer Films: Designed Synthesis, Conducting Properties, and Photoenergy Conversions
Gu, Cheng,Huang, Ning,Chen, Youchun,Qin, Leiqiang,Xu, Hong,Zhang, Shitong,Li, Fenghong,Ma, Yuguang,Jiang, Donglin
, p. 13594 - 13598 (2015/11/16)
Conjugated microporous polymers are a unique class of polymers that combine extended π-conjugation with inherent porosity. However, these polymers are synthesized through solution-phase reactions to yield insoluble and unprocessable solids, which preclude
Synthesis, polymerization, and unusual properties of new star-shaped thiophene oligomers
Taerum, Tyler,Lukoyanova, Olena,Wylie, Ryan G.,Perepichka, Dmitrii F.
supporting information; experimental part, p. 3230 - 3233 (2009/11/30)
Terthienobenzene (TTB, 6) was prepared through a new, high yield route along with π-extended derivatives 10 and 11. Electropolymerization of trs-EDOT derivative 11 results in a highly stable cross-linked conjugated polymer that shows polaron confinement b