1426678-15-0

Basic information

• Product Name: (R)-6-fluoro-3-hydroxy-3-phenyl-1-tosyl-2,3-dihydroquinolin-4(1H)-one
• CAS NO: 1426678-15-0
• Molecular Weight: 411.454
• Mol File: 1426678-15-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-6-fluoro-3-hydroxy-3-phenyl-1-tosyl-2,3-dihydroquinolin-4(1H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-6-fluoro-3-hydroxy-3-phenyl-1-tosyl-2,3-dihydroquinolin-4(1H)-one(1426678-15-0)
• EPA Substance Registry System: (R)-6-fluoro-3-hydroxy-3-phenyl-1-tosyl-2,3-dihydroquinolin-4(1H)-one(1426678-15-0)

Safety Data

• Hazardous Substances Data: 1426678-15-0(Hazardous Substances Data)

Upstream product

• 748805-85-8 (2-amino-5-fluorophenyl)methanol 
• 1426677-83-9 N-(4-fluoro-2-formylphenyl)-4-methyl-N-(2-oxo-2-phenylethyl)benzenesulfonamide 
• 1426678-00-3 C₂₂H₂₀FNO₄S 
• 446-08-2 2-amino-5-fluorobenzoic acid 
• 1426677-90-8 N-(4-fluoro-2-(hydroxymethyl)phenyl)-4-methylbenzenesulfonamide 

Relevant articles and documents

N-heterocyclic carbene-catalyzed enantioselective intramolecular N-tethered aldehyde-ketone benzoin reactions

The N-heterocyclic carbene-catalyzed enantioselective intramolecular benzoin reaction of N-tethered substrates was realized. With 15 mol % of d-camphor-derived triazolium salt E and 10 mol % of NaOAc, the aldehyde-ketone cross benzoin reactions of various substituted N-tethered substrates proceeded smoothly to afford dihydroquinolinone derivatives with a quaternary carbon stereocenter in moderate to good yields and excellent ee.