1427777-81-8

Basic information

• Product Name: (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate
• Synonyms: (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate
• CAS NO: 1427777-81-8
• Molecular Weight: 350.315
• Mol File: 1427777-81-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate(1427777-81-8)
• EPA Substance Registry System: (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate(1427777-81-8)

Safety Data

• Hazardous Substances Data: 1427777-81-8(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 1403959-51-2 ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Relevant articles and documents

Sigmatropic rearrangement of allenic alcohols: Stereoselective synthesis of 1,3-diene-2-ol sulfonates

An efficient synthetic pathway to 1,3-diene-2-ol sulfonates involving the [3,3]-sigmatropic rearrangement of allenic alcohols with sulfonic acids under mild reaction conditions is described. These products can easily undergo reduction or transition-metal catalyzed cross-coupling reactions to yield a series of stereodefined multisubstituted 1,3-dienes.