1403959-51-2

Basic information

• Product Name: ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate
• Synonyms: ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate
• CAS NO: 1403959-51-2
• Molecular Weight: 218.252
• Mol File: 1403959-51-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate(1403959-51-2)
• EPA Substance Registry System: ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate(1403959-51-2)

Safety Data

• Hazardous Substances Data: 1403959-51-2(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 

Downstream Products

• 1427778-21-9 C₁₃H₁₃ClO₂ 
• 1427778-16-2 C₁₃H₁₃BrO₂ 
• 1427778-18-4 C₁₃H₁₃BrO₂ 
• 1427777-81-8 (2E,4E)-ethyl 5-phenyl-3-(((trifluoromethyl)sulfonyl)oxy)penta-2,4-dienoate 
• 20708-10-5 C₁₃H₁₄O₃ 
• 41436-07-1 ethyl (2Z,4E)-3-methyl-5-phenyl-2,4-pentanedienoate 
• 41436-08-2 ethyl (2E,4E)-3-methyl-5-phenyl-2,4-pentanedienoate 
• 19367-40-9 (2E,4E)-3,5-diphenylpentadienoic acid ethyl ester 

Relevant articles and documents

Synthesis of 5,6-Dihydropyrazolo[5,1-a]isoquinoline and Ethyl (Z)-3-Acetoxy-3-tosylpent-4-enoate through Tertiary-Amine-Catalyzed [3+2] Annulation

The 1,4-diazabicyclo[2.2.2]octane (DABCO) catalyzed divergent [3+2] annulation of C,N-cyclic azomethine imines with δ-acetoxyallenoates was developed; 5,6-dihydropyrazolo[5,1-a]isoquinolines and ethyl (Z)-3-acetoxy-3-tosylpent-4-enoates were afforded in moderate to good yields in a one-pot manner under mild conditions. This annulation reaction provides a highly efficient method to construct dinitrogen-fused heterocycles and ethyl (Z)-3-acetoxy-3-tosylpent-4-enoates at the same time.

Lewis base-catalyzed divergent isomerizations of 5-hydroxyl-2,3-dienoate

A divergent isomerization of 5-hydroxyl-2,3-dienoate 1 catalyzed by Lewis base has been developed, the phosphine catalyst leads to 5-oxohex-2(3)-enoates 2 while DABCO catalyst affords 3-ethoxy α,β-unsaturated lactone 3.