19367-40-9Relevant articles and documents
Sigmatropic rearrangement of allenic alcohols: Stereoselective synthesis of 1,3-diene-2-ol sulfonates
Zhao, Yuyang,Wang, Yurong,Gu, Zhanshou,Wang, Zhiming
, p. 4014 - 4021 (2017/07/11)
An efficient synthetic pathway to 1,3-diene-2-ol sulfonates involving the [3,3]-sigmatropic rearrangement of allenic alcohols with sulfonic acids under mild reaction conditions is described. These products can easily undergo reduction or transition-metal catalyzed cross-coupling reactions to yield a series of stereodefined multisubstituted 1,3-dienes.