1427778-16-2

Basic information

• Product Name: C₁₃H₁₃BrO₂
• Synonyms: C₁₃H₁₃BrO₂
• CAS NO: 1427778-16-2
• Molecular Weight: 281.149
• Mol File: 1427778-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₃BrO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₃BrO₂(1427778-16-2)
• EPA Substance Registry System: C₁₃H₁₃BrO₂(1427778-16-2)

Safety Data

• Hazardous Substances Data: 1427778-16-2(Hazardous Substances Data)

Upstream product

• 1403959-51-2 ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 

Relevant articles and documents

Subtle electronic effects in metal-free rearrangement of allenic alcohols

A general and stereoselective rearrangement of allenic alcohols to (E,E)-1,3-dien-2-yl triflates and chlorides was developed under metal-free conditions. Subtle electronic effects of the alkyl and aryl substituents on the carbon bearing the hydroxyl group has a profound impact on the reaction rate and efficiency such that vinyl triflates were obtained from electron-deficient substrates and trimethylsilyl triflate whereas vinyl chlorides were generated with an electron-rich substrate and trimethylsilyl chloride.