41436-07-1

Basic information

• Product Name: 2,4-Pentadienoic acid, 3-methyl-5-phenyl-, ethyl ester, (2Z,4E)-
• CAS NO: 41436-07-1
• Molecular Formula: C14H16O2
• Molecular Weight: 216.28
• Mol File: 41436-07-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2,4-Pentadienoic acid, 3-methyl-5-phenyl-, ethyl ester, (2Z,4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Pentadienoic acid, 3-methyl-5-phenyl-, ethyl ester, (2Z,4E)-(41436-07-1)
• EPA Substance Registry System: 2,4-Pentadienoic acid, 3-methyl-5-phenyl-, ethyl ester, (2Z,4E)-(41436-07-1)

Safety Data

• Hazardous Substances Data: 41436-07-1(Hazardous Substances Data)

Upstream product

• 105-36-2 ethyl bromoacetate 
• 1896-62-4 (E)-benzalacetone 
• 623-73-4 diazoacetic acid ethyl ester 
• 100-42-5 styrene 
• 130484-18-3 ethyl (2Z,4E)-3-methylhexa-2,4-dienoate 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 1403959-51-2 ethyl 5-hydroxy-5-phenylpenta-2,3-dienoate 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 20430-09-5 (2Z,4E)-3-methyl-5-phenylpenta-2,4-dienoic acid 
• 20430-13-1 (2E,4E)-3-methyl-5-phenyl-2,4-pentadienoic acid 

Relevant articles and documents

Selective synthesis of (2Z,4E)-dienyl esters by ene-diene cross metathesis

(Chemical Equation Presented) Cross metathesis of terminal alkenes with methyl (2Z4E)-hexadienoate and related dienyl esters provides substituted (2Z,4E)-dienyl esters in good yields. Small-scale reactions are effectively promoted by the standard second-g

A newly-designed PE-supported arsine for efficient and practical catalytic Wittig olefination

A newly designed PE-supported arsine has been developed as an excellent catalyst for catalytic Wittig-type olefination. Simple ketones, in particular inactive ketones prove to be suitable substrates for the first time. This reaction provides an easy access to di-, tri-, and tetra-substituted olefins in high yield.

Acid-promoted olefination of ketones by an iron(III) porphyrin complex

(Matrix presented) The acid-promoted olefination of unactivated ketones with diazo reagents in the presence of triphenylphosphine can be catalyzed by the commercially available iron(III) porphyrin complex Fe(TPP)Cl. The reactions were effectively carried out under mild conditions in a one-pot fashion with the use of a stoichiometric diazo reagents and substoichiometric benzoic acid. Examples include aromatic, aliphatic, cyclic, and unsaturated ketones with ethyl diazoacetate or tert-butyl diazoacetate.