14297-34-8

Basic information

• Product Name: 2-(4-BROMOPHENYL)FURAN
• Synonyms: 4-BROMO-(2-FURYL)BENZENE;AKOS 91622;2-(4-BROMOPHENYL)FURAN;2-(4-Bromophenyl)furan 97%;2-(4-Bromophenyl)furan97%
• CAS NO: 14297-34-8
• Molecular Formula: C₁₀H₇BrO
• Molecular Weight: 223.07
• Product Categories: Furan&Benzofuran
• Mol File: 14297-34-8.mol
• Article Data: 45

Chemical Properties

• Melting Point: 83-84.5
• Boiling Point: 277.4 °C at 760 mmHg
• Flash Point: 121.5 °C
• Appearance: /
• Density: 1.451 g/cm³
• Vapor Pressure: 0.00767mmHg at 25°C
• Refractive Index: 1.575
• CAS DataBase Reference: 2-(4-BROMOPHENYL)FURAN(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-BROMOPHENYL)FURAN(14297-34-8)
• EPA Substance Registry System: 2-(4-BROMOPHENYL)FURAN(14297-34-8)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 14297-34-8(Hazardous Substances Data)

Usage

General Description

2-(4-Bromophenyl)furan is a chemical compound with the molecular formula C10H7BrO. It is a heterocyclic organic compound that contains a furan ring with a bromine substitution on the phenyl group at the 4-position. This chemical is commonly used in the synthesis of pharmaceuticals, agrochemicals, and electronic materials. It is known for its aromatic and heterocyclic properties, making it a versatile building block in organic synthesis. 2-(4-Bromophenyl)furan has also been studied for its potential biological and pharmacological activities, including its potential as an anticancer agent and as a ligand for various receptors in the body.

InChI:InChI=1/C10H7BrO/c11-9-5-3-8(4-6-9)10-2-1-7-12-10/h1-7H

Upstream product

• 110-00-9 furan 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 106-40-1 4-bromo-aniline 
• 622-88-8 4-bromophenylhydrazine hydrochloride 
• 5467-74-3 4-Bromophenylboronic acid 
• 6165-76-0 propargyl p-toluenesulfonate 
• 378186-96-0 1-(4-bromophenyl)-2,3-butadien-1-one 
• 589-87-7 1,4-bromoiodobenzene 
• 118486-94-5 2-(tributylstannyl)furan 
• 13331-23-2 fur-2-ylboronic acid 
• 10160-87-9 Propiolaldehyde diethyl acetal 
• 1122-91-4 4-bromo-benzaldehyde 
• 1210927-96-0 C₁₂H₁₃BrO 
• 1210927-97-1 2-(4-bromophenyl)-2,5-dihydrofuran 

Downstream Products

• 64468-77-5 2-(4-cyanophenyl)furan 
• 84185-75-1 4-(4-Bromo-phenyl)-7-hydroxy-isobenzofuran-1,3-dione 
• 84185-81-9 (E)-2-[5-(4-Bromo-phenyl)-furan-2-yl]-but-2-enedioic acid 
• 73226-75-2 2-Bromo-5-(p-bromophenyl)furan 
• 73226-92-3 3,5-Dibromo-2-(p-bromophenyl)furan 
• 194221-03-9 4'-Bromo-4-hydroxy-biphenyl-2,3-dicarboxylic acid dimethyl ester 
• 73226-95-6 3-Bromo-2-(p-bromophenyl)furan 
• 1018987-52-4 3-[4-(2-furyl)phenyl]-2-propyn-1-ol 
• 1040428-22-5 (R)-[5-(4-bromo-phenyl)furan-2-yl]hydroxyacetic acid butyl ester 

Relevant articles and documents

Interface coassembly of mesoporous MoS2 based-frameworks for enhanced near-infrared light driven photocatalysis

The three-dimensional porous Fe3O4@Cu2-xS-MoS2 framework is reported for the first time. The as-prepared 3D framework exhibits good structural stability, high surface area, enhanced adsorption capacity to substrates, and strong absorption in the NIR range. As a result, such hybrid frameworks exhibit excellent NIR-light photocatalytic activity and stable cycling for the direct arylation of heteroaromatics at room temperature.

Gram-scale synthesis of aligned C3N4-polypyrrole heterojunction aerogels with tunable band structures as efficient visible and near infrared light-driven metal-free photocatalysts

The assembly of aligned porous materials from simple building blocks is of widespread interest for engineering materials with enhanced and synergistic properties. To date, however, how to develop 3D heterojunction aerogels with aligned porosity based on 2D semiconductor materials and 1D conducting polymers for solar energy conversion in the visible and near-infrared (NIR) light region remains a significant challenge. Here a new class of gram-scale 3D aligned heterojunction aerogels of polypyrrole (PPy)/C3N4 nanosheets (NSs) were designed and synthesized by directional freezing of polypyrrole (PPy)/polyvinyl alcohol (PVA) and C3N4 NS aqueous suspension. The synthesis of aligned C3N4-PPy heterojunction aerogels can be achieved on a large scale. The formed aerogel expresses stable and uniform dispersion of the two building blocks, long-range channel aligned structures along the whole monolithic sample, and additional special complementary optical properties between PPy and C3N4 NSs. Based on the above unique structure and optical properties, this novel metal-free heterojunction aerogel exhibits excellent photocatalytic activity and long-term stability for direct arylation of heteroaromatics under visible and near infrared (NIR) light irradiation at room temperature, far exceeding those of the single- and two-component systems. Our work therefore not only provides a new approach to obtain aligned heterojunction aerogels based on metal free semiconductors but also paves a way to develop gram-scale aerogels as a new type of highly efficient visible and NIR light induced heterogeneous photocatalyst.

Synthesis of 2,5-Disubstituted Furans from Sc(OTf)3 Catalyzed Reaction of Aryl Oxiranediesters with γ-Hydroxyenones

A convenient synthesis of 2,5-disubstituted furan was developed by employing donor-acceptor oxiranes in a new reaction with γ-hydroxyenones. Sc(OTf)3 was found to be the best catalyst, and 2,5-disubstituted furans are obtained in moderate to good yields under mild reaction conditions. The scope of the reaction is quite decent, allowing for the synthesis of disubstituted furans having aryl and heteroaromatic groups.

Fabrication of Graphitic Carbon Nitride-Based Film: An Emerged Highly Efficient Catalyst for Direct C—H Arylation under Solar Light

Photoredox C—H bond formation can proceed in aerobic environment under solar light and has therefore become attractive. Nowadays, different types of expensive novel metal complexes and nanomaterials have been urbanized as photocatalysts for direct C—H bon

Mild and Robust Stille Reactions in Water using Parts Per Million Levels of a Triphenylphosphine-Based Palladacycle

An inexpensive and new triphenylphosphine-based palladacycle has been developed as a pre-catalyst, leading to highly effective Stille cross-coupling reactions in water under mild reaction conditions. Only 500–1000 ppm of Pd suffices for couplings involving a variety of aryl/heteroaryl halides with aryl/hetaryl stannanes. Several drug intermediates can be prepared using this catalyst in aqueous nanoreactors formed by 2 wt % Brij-30 in water.

Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes

Black phosphorus (BP) is for the first time employed as a metal-free, heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes with aryl diazonium salts. The arylated heteroarenes are obtained in moderate to good yields under visible-light illumination, and the protocol is shown to be applicable for the scale-up synthesis.