143839-64-9

Basic information

• Product Name: Propanoyl chloride, 2-(2,4-dichlorophenoxy)-, (2R)-
• CAS NO: 143839-64-9
• Molecular Formula: C9H7Cl3O2
• Molecular Weight: 253.512
• Mol File: 143839-64-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Propanoyl chloride, 2-(2,4-dichlorophenoxy)-, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoyl chloride, 2-(2,4-dichlorophenoxy)-, (2R)-(143839-64-9)
• EPA Substance Registry System: Propanoyl chloride, 2-(2,4-dichlorophenoxy)-, (2R)-(143839-64-9)

Safety Data

• Hazardous Substances Data: 143839-64-9(Hazardous Substances Data)

Upstream product

• 120-36-5 (R)-dichlorprop 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 115852-48-7 N-(1-cyano-1,2-dimethyl-propyl)-2-(2,4-dichlorophenoxy)-propionamide 
• 305819-40-3 methyl (2R)-[N-(2,4-dichlorophenoxy)propanoyl]glycinate 

Relevant articles and documents

A photochemical approach to phenylalanines and related compounds by alkylation of glycine

Phenylalanines can be prepared on UV photolysis of protected glycines in the presence of di-tert-butyl peroxide, substituted toluenes and the photosensitiser benzophenone. These reactions, which lead to highly selective mono-alkylation at the α-position of glycines, involve coupling of captodative α-glycine radicals with benzyl radicals. This method can be used to selectively alkylate a variety of glycine derivatives using a range of substituted toluenes under neutral reaction conditions.