143878-63-1

Basic information

• Product Name: (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene
• Synonyms: (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene
• CAS NO: 143878-63-1
• Molecular Weight: 208.257
• Mol File: 143878-63-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene(143878-63-1)
• EPA Substance Registry System: (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene(143878-63-1)

Safety Data

• Hazardous Substances Data: 143878-63-1(Hazardous Substances Data)

Upstream product

• 143878-62-0 (4S,5S)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 
• 144536-31-2 (4S,5S)-4-Benzyloxymethyl-5-vinyl-[1,3]dioxolan-2-one 
• 182206-15-1 (2S,3S)-1-(benzyloxy)-3-(4-methoxyphenoxy)pent-4-en-2-ol 
• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 

Downstream Products

• 160699-77-4 (5S,6S)-5-hydroxy-6-[(E)-styryl]-5,6-dihydro-2H-pyran-2-one 
• 1535176-85-2 (2R,3S)-2-(benzyloxy)-3-(tert-butyldimethylsilyloxy)pent-4-enal 
• 1535176-84-1 (2S,3S)-2-(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)pent-4-en-1-ol 
• 147219-88-3 {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene 
• 212370-47-3 (E,2S,3S)-1-(benzyloxy)-5-phenylpent-4-ene-2,3-diol 
• 144536-31-2 (4S,5S)-4-Benzyloxymethyl-5-vinyl-[1,3]dioxolan-2-one 

Relevant articles and documents

Stereoselective Synthesis of C1–C7 and C6–C22 Fragments of Phostriecin, Goniothalamines, and Their Analogues

The stereoselective synthesis of two fragments (C1–C7 and C6–C22) of the anti-tumor agent phostriecin has been achieved. The chiral hydroxy-vinyl-δ-lactone building block (fragment C1–C7) was subsequently utilized for the synthesis of 5-hydroxygoniothalamin, 5-acetoxygoniothalamin, and their derivatives.

[(Z)-γ-[(diisopropylidene-α-D-mannopyranosyl)oxy]allyl]- tributylstannane: A new chiral reagent for the asymmetric α-hydroxyallylation of aldehydes

Reactions of [(Z)-γ- [(diisopropylidene-α-D-mannopyranosyl)oxy]allyl]tributylstannane (6) with several chiral and achiral aldehydes are described. This reagent was designed in anticipation that significant diastereofacial bias in reactions with aldehydes

(E)-γ-substituted allylic alcohols and α-substituted homoallylic alcohols via acidic treatment of the acetonides derived from γ-substituted vinyl diols

Treatment of the acetonides of γ-substituted vinyl diols under acidic deprotection conditions afforded γ-substituted allylic alcohols and α-substituted homallylic alcohols.