147219-88-3

Basic information

• Product Name: {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene
• Synonyms: {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene
• CAS NO: 147219-88-3
• Molecular Weight: 174.243
• Mol File: 147219-88-3.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene(CAS DataBase Reference)
• NIST Chemistry Reference: {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene(147219-88-3)
• EPA Substance Registry System: {[(2E)-penta-2,4-diene-1-yloxy]methyl}benzene(147219-88-3)

Safety Data

• Hazardous Substances Data: 147219-88-3(Hazardous Substances Data)

Upstream product

• 60656-87-3 benzyloxyacetoaldehyde 
• 156701-45-0 2-(prop-2-enylsulfonyl)benzothiazole 
• 273730-83-9 1-phenyl-5-(prop-2'-ene-1'-sulfonyl)-1H-tetrazole 
• 75927-49-0 pinacol vinylboronate 
• 610272-48-5 1-[((E)-3-bromoallyloxy)methyl]benzene 
• 13369-23-8 ethyl (2E)-penta-2,4-dienoate 
• 17891-78-0 1,3-bis(trimethylsilyl)propene 
• 143878-62-0 (4S,5S)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 
• 143878-63-1 (3S,4S)-5-benzyloxy-syn-3,4-dihydroxy-1-pentene 
• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 
• 2409-87-2 methyl (2E)-penta-2,4-dienoate 
• 21651-12-7 (E)-2,4-pentadienoic acid 
• 1826-67-1 vinyl magnesium bromide 
• 100-39-0 benzyl bromide 

Downstream Products

• 98540-12-6 (+/-)-(1R,2S,6S)-1,2-bis(iodomethyl)-1,6-dimethylcyclohexane 
• 98540-11-5 (1RS,2SR,3SR)-2-(hydroxymethyl-2,3-dimethylcyclohexyl)methanol 

Relevant articles and documents

Synthesis of spiroindanes by palladium-catalyzed oxidative annulation of non- or weakly activated 1,3-dienes involving C-H functionalization

The synthesis of spiroindanes by the palladium-catalyzed oxidative annulation of non- or weakly activated 1,3-dienes with 2-aryl cyclic 1,3-dicarbonyl compounds is described. Examples of the dearomatizing oxidative annulation of 1,3-dienes with 1-aryl-2-naphthols are also presented. This journal is

Rhodium-Catalyzed Oxidative C-H Allylation of Benzamides with 1,3-Dienes by Allyl-to-Allyl 1,4-Rh(III) Migration

The Rh(III)-catalyzed oxidative C-H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a proposed mechanism is provided. The key step is postulated to be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration.

Lewis acid-promoted addition of 1,3-bis(silyl)propenes to aldehydes: A route to 1,3-dienes

The Lewis acid-promoted addition of 1,3-bis(silyl)-propenes to aldehydes to provide the corresponding (E)-1,3-dienes in excellent stereoselectivity and good to excellent yields is reported. The procedure is mild, base-free, and operationally straightforward.