144266-44-4

Basic information

• Product Name: Cyclohexane, 4-methyl-1-(1-methylethyl)-2-(2-propenyloxy)-
• CAS NO: 144266-44-4
• Molecular Formula: C13H24O
• Molecular Weight: 196.333
• Mol File: 144266-44-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 4-methyl-1-(1-methylethyl)-2-(2-propenyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 4-methyl-1-(1-methylethyl)-2-(2-propenyloxy)-(144266-44-4)
• EPA Substance Registry System: Cyclohexane, 4-methyl-1-(1-methylethyl)-2-(2-propenyloxy)-(144266-44-4)

Safety Data

• Hazardous Substances Data: 144266-44-4(Hazardous Substances Data)

Upstream product

• 27303-99-7 sodium menthoxide 
• 106-95-6 allyl bromide 
• 2216-51-5 (-)-menthol 
• 556-56-9 allyl iodid 
• 180477-54-7 (1S,2R,4R)-1-isopropyl-4-methyl-2-(3-methylbut-2-en-1-yloxy)cyclohexane 
• 195863-85-5 (1S,2R,4R)-1-isopropyl-4-methyl-2-(2-methylprop-2-en-1-yloxy)cyclohexane 
• 753488-83-4 (1S,2R,4R)-2-(2,3-dimethylbut-2-en-1-yloxy)-1-isopropyl-4-methylcyclohexane 
• 136375-73-0 [[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]benzene 
• 101-37-1 triallyl cyanurate 
• 15356-70-4 menthol 

Downstream Products

• 19876-26-7 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 
• 19876-20-1 Chloro-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 
• 20054-84-6 Menthoxypropyl-ethyl-dichlor-silan 
• 19876-24-5 Diethoxy-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-methyl-silane 
• 89-78-1 menthol 
• 19876-25-6 triethoxy(3-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)- propyl)silane 
• 22565-10-2 1-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]propan-2-one 
• 1384544-25-5 (E)-(1S,2R,4R)-1-isopropyl-4-methyl-2-(prop-1-enyloxy)cyclohexane 
• 107941-60-6 (1S,2R,4R)-1-isopropyl-4-methyl-2-((Z)-prop-1-en-1-yloxy)cyclohexane 
• 1204045-48-6 2-N-phenoxyacetyl-6-(3-O-L-menthylpropenyl)-9-(3',5'-di-O-t-butyldimethylsilyl-2'-deoxy-β-D-ribofuranosyl)purine 
• 107941-60-6 (1S,2R,4R)-1-Isopropyl-4-methyl-2-[((E)-propenyl)oxy]-cyclohexane 
• 19876-31-4 1,3-Bis-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-1,1,3,3-tetramethyl-disiloxane 
• 19876-23-4 Ethoxy-[3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-propyl]-dimethyl-silane 
• 76993-60-7 (4aS,7aS,11aR,11bR)-6-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxymethyl)-dodecahydro-5,7-dioxa-dibenzo[a,c]cycloheptene 

Relevant articles and documents

Study of O-allylation using triazine-based reagents

Acid-catalyzed allylating reagent 2,4,6-tris(allyloxy)-1,3,5-triazine (TriAT-allyl) and its substituted derivatives have been developed. The reaction of acid-, and alkali-labile alcohols with these reagents in the presence of a catalytic amount of trifluoromethanesulfonic acid (TfOH) afforded the corresponding allyl ethers in good yields. Reactions using these reagents with an unsymmetrically-substituted regioisometric allyl group suggested that a single isometric allylic cation species would be involved.

Nickel Hydride Catalyzed Cleavage of Allyl Ethers Induced by Isomerization

This report discloses the deallylation of O - and N -allyl functional groups by using a combination of a Ni-H precatalyst and excess Bronsted acid. Key steps are the isomerization of the O - or N -allyl group through Ni-catalyzed double-bond migration followed by Bronsted acid induced O/N-C bond hydrolysis. A variety of functional groups are tolerated in this protocol, highlighting its synthetic value.

Isomerization of allyl ethers initiated by lithium diisopropylamide

Lithium diisopropylamide (LDA) promotes virtually quantitative conversion of allylic ethers to (Z)-propenyl ethers. It was discovered that allylic ethers can be isomerized efficiently with very high stereoselectivity to (Z)-propenyl ethers by LDA in THF a