1443256-45-8

Basic information

• Product Name: (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol
• Synonyms: (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol
• CAS NO: 1443256-45-8
• Molecular Weight: 392.623
• Mol File: 1443256-45-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol(1443256-45-8)
• EPA Substance Registry System: (3S,5R)-1-(4-hydroxyphenyl)nonadecane-3,5-diol(1443256-45-8)

Safety Data

• Hazardous Substances Data: 1443256-45-8(Hazardous Substances Data)

Upstream product

• 1258516-47-0 {(1S)-3-[4-(benzyloxy)phenyl]-1-{[(2S)-oxiran-2-yl]methyl}propoxy}(tert-butyl)dimethylsilane 
• 1638640-11-5 C₂₅H₃₆O₃Si 
• 1638640-04-6 ({(3S)-1-[4-(benzyloxy)phenyl]hex-5-en-3-yl}oxy)(tert-butyl)(dimethyl)silane 
• 767330-04-1 (-)-(3S)-1-[4-(benzyloxy)phenyl]hex-5-en-3-ol 
• 1010127-34-0 (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane 
• 944335-23-3 (2S)-4-[4-(benzyloxy)phenyl]-2-hydroxybutyl 4-methyl-1-benzenesulfonate 
• 944335-22-2 (2S)-4-[4-(benzyloxy)phenyl]butane-1,2-diol 
• 1638640-10-4 C₂₃H₂₅NO₃ 
• 69172-21-0 4-(4-Benzyloxyphenyl)butanal 
• 1166181-77-6 methyl 4-[4-(benzyloxy)phenyl]butanoate 
• 243641-03-4 C₁₈H₁₈O₃ 
• 1569102-73-3 (2S,4R,6S)-2-(4-methoxyphenylethyl)tetrahydro-6-(hydroxymethyl)-2H-pyran-4-ol 
• 56438-60-9 2-[2-(4-methoxyphenyl)ethyl]-1,3-dithiane 
• 1569102-86-8 (R)-1-(2-(4-methoxyphenylethyl)-1,3-dithian-2-yl)pent-4-en-2-ol 

Relevant articles and documents

Stereoselective total synthesis of phenolic nonadecanediol

A simple and highly efficient synthetic route has been developed for synthesis of 1-(4-hydroxyphenyl)nonadecane-3,5-diol (1). The two stereogenic centers were generated by employing proline asymmetric α-hydroxylation (MacMillan α-hydroxylation), Jacobsen's hydrolytic kinetic resolution (HKR), and, finally, Yamaguchi oxirane opening as key steps (Scheme 2). Copyright

Synthesis and configuration of the phenolic nonadecanediol isolated from the resinous exudates of heliotropium sinuatum

The (3S,5R) and (3R,5R) isomers of the title compound were synthesized from enantiopure epoxide chiral building blocks readily accessible from D-gluconolactone. The former (a syn-1,3-diol) gave 1H and 13C NMR spectroscopic data and optical rotation in good agreement with those reported for the natural product, whereas distinct differences were found with the data for the latter (an anti-1,3-diol). These results unambiguously showed that the absolute configuration of the natural product must be (3S,5R).