144479-03-8

Basic information

• Product Name: Benzene, [3-(phenylmethoxy)-1-propynyl]-
• CAS NO: 144479-03-8
• Molecular Formula: C16H14O
• Molecular Weight: 222.287
• Mol File: 144479-03-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, [3-(phenylmethoxy)-1-propynyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [3-(phenylmethoxy)-1-propynyl]-(144479-03-8)
• EPA Substance Registry System: Benzene, [3-(phenylmethoxy)-1-propynyl]-(144479-03-8)

Safety Data

• Hazardous Substances Data: 144479-03-8(Hazardous Substances Data)

Upstream product

• 30379-55-6 benzyloxyacetic acid 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 100-51-6 benzyl alcohol 
• 108-86-1 bromobenzene 
• 4039-82-1 Benzyl propargyl ether 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 107383-25-5 (3-benzyloxy-prop-1-ynyl)trimethylsilanebenzyl ether 
• 2023-48-5 triphenylbismuth(V) difluoride 
• 3587-60-8 Benzyloxymethyl chloride 
• 3757-88-8 tributylstannylethynylbenzene 
• 591-50-4 iodobenzene 

Downstream Products

• 122-97-4 3-Phenyl-1-propanol 
• 70770-06-8 1-benzyloxy-3-phenylpropane 
• 1187226-17-0 C₂₀H₂₀O₃ 
• 1187226-10-3 C₂₀H₂₀O₃ 
• 1203825-70-0 (E)-1-((1-fluoro-4-phenyl-1,1-bis(phenylsulfonyl)but-3-en-2-yloxy)methyl)benzene 
• 2327-99-3 1-phenylpropadiene 
• 1226870-16-1 (3-(benzyloxy)prop-1-ene-1,1-diyl)dibenzene 
• 1226870-20-7 C₂₂H₂₀O 
• 1226968-28-0 3-benzyloxy-2-diphenylphosphinyl-1-phenyl-1-propene 
• 1259284-08-6 C₂₂H₂₅NO₂ 
• 1259284-05-3 C₂₄H₂₁NO₂ 
• 1343516-37-9 3-(1-(benzyloxy)-3-phenylprop-2-ynyl)-3-methylpentane-2,4-dione 

Relevant articles and documents

Graphitic Carbon Nitride Polymer as a Recyclable Photoredox Catalyst for Decarboxylative Alkynylation of Carboxylic Acids

Visible-light-induced heterogeneous photocatalysis for decarboxylative alkynylation has been performed. The using of cheap, metal-free and recyclable graphitic carbon nitride (g-C3N4) as the photoredox catalyst in the process enables

Iron(II) chloride catalyzed alkylation of propargyl ethers: Direct functionalization of an sp3 C-H bond adjacent to oxygen

Iron(II) chloride catalyzed direct alkylation of sp3 C-H bond adjacent to oxygen in propargyl ethers has been accomplished by the use of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as oxidant under mild reaction conditions. The reaction proceeded smoothly with a variety of 1,3-diketones leading to -dicarbonyl ether in moderate yields. In the absence of 1,3-diketones, ynenones were produced by the use of iron(III) chloride and DDQ. Georg Thieme Verlag Stuttgart - New York.

Gold(I)-catalyzed rearrangement of propargyl benzyl ethers: A practical method for the generation and in situ transformation of substituted allenes

A series of benzyl propargyl ethers react with a gold(I) catalyst to furnish variously substituted allenes via a 1,5-hydride shift/fragmentation sequence. This transformation is rapid and practical. It can be performed under very mild conditions (room temperature or 60 °C) using terminal as well as substituted alkyne substrates bearing a primary, secondary, or tertiary benzyl ether group. The allenes thus formed can be reacted in situ with an internal or external nucleophile, corresponding to an overall reductive substitution process, to produce more functionalized compounds.