1446135-59-6

Basic information

• Product Name: 3-[bromo(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide
• Synonyms: 3-[bromo(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide
• CAS NO: 1446135-59-6
• Molecular Weight: 422.162
• Mol File: 1446135-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[bromo(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[bromo(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide(1446135-59-6)
• EPA Substance Registry System: 3-[bromo(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide(1446135-59-6)

Safety Data

• Hazardous Substances Data: 1446135-59-6(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 844658-92-0 (R)-(-)-[1-phenylethyl]-1H-imidazole 

Downstream Products

• 1446135-61-0 3-[(tert-butylthio)(phenyl)methyl]-1-((R)-1-phenylethyl)-1H-imidazol-3-ium bromide 

Relevant articles and documents

Synthesis, structural characterisation and stereochemical investigation of chiral sulfur-functionalised N-heterocyclic carbene complexes of palladium and platinum

Palladium and platinum complexes containing a sulfur-functionalised N-heterocyclic carbene (S-NHC) chelate ligand have been synthesised. The absolute conformations of these novel organometallic S-NHC chelates were determined by X-ray structural analyses and solution-phase 2D 1H-1H ROESY NMR spectroscopy. The structural studies revealed that the phenyl substituents on the stereogenic carbon atoms invariably take up the axial positions on the Pd-C-S coordination plane to afford a skewed five-membered ring structure. All of the chiral complexes are structurally rigid and stereochemically locked in a chiral ring conformation that is either (Rs,S,R)-λ or (Ss,R,R)-δ in both the solid state and solution. Copyright