1449105-45-6

Basic information

• Product Name: 8-(4-acetamidostyryl)-4,4-difluoro-1,3,5-trimethyl-4-bora-3a,4a-diaza-s-indacene
• Synonyms: 8-(4-acetamidostyryl)-4,4-difluoro-1,3,5-trimethyl-4-bora-3a,4a-diaza-s-indacene
• CAS NO: 1449105-45-6
• Molecular Weight: 393.244
• Mol File: 1449105-45-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-(4-acetamidostyryl)-4,4-difluoro-1,3,5-trimethyl-4-bora-3a,4a-diaza-s-indacene(CAS DataBase Reference)
• NIST Chemistry Reference: 8-(4-acetamidostyryl)-4,4-difluoro-1,3,5-trimethyl-4-bora-3a,4a-diaza-s-indacene(1449105-45-6)
• EPA Substance Registry System: 8-(4-acetamidostyryl)-4,4-difluoro-1,3,5-trimethyl-4-bora-3a,4a-diaza-s-indacene(1449105-45-6)

Safety Data

• Hazardous Substances Data: 1449105-45-6(Hazardous Substances Data)

Upstream product

• 1449105-34-3 4,4-difluoro-1,3,5,8-tetramethyl-4-bora-3a,4a-diaza-s-indacene 
• 122-85-0 para-acetamidobenzaldehyde 
• 636-41-9 2-methyl-1H-pyrrole 
• 1500-93-2 1-(3,5-dimethyl-1H-pyrrol-2-yl)ethan-1-one 

Relevant articles and documents

8-Functionalization of alkyl-substituted-3,8-dimethyl BODIPYs by Knoevenagel condensation

New 8-alkenylBODIPYs have been synthesized by Knoevenagel condensation between a series of alkyl-substituted-3,8-dimethylBODIPYs and aromatic or aliphatic aldehydes. This is in clear contrast with literature precedents, which indicate that this reaction occurs exclusively on the methyl group at C-3. The change in hybridization of the carbon at the 8-position (from sp3 to sp2) determines the fluorescence emission of the BODIPY, while the presence of electron-donating or -withdrawing groups leads to intramolecular charge transfer processes.