1452128-85-6

Basic information

• Product Name: (E)-3-phenyl-2-(p-tolyl)acrylaldehyde
• Synonyms: (E)-3-phenyl-2-(p-tolyl)acrylaldehyde
• CAS NO: 1452128-85-6
• Molecular Weight: 222.287
• Mol File: 1452128-85-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-3-phenyl-2-(p-tolyl)acrylaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-phenyl-2-(p-tolyl)acrylaldehyde(1452128-85-6)
• EPA Substance Registry System: (E)-3-phenyl-2-(p-tolyl)acrylaldehyde(1452128-85-6)

Safety Data

• Hazardous Substances Data: 1452128-85-6(Hazardous Substances Data)

Upstream product

• 103-54-8 cinnamyl acetate 
• 624-31-7 4-tolyl iodide 
• 77134-00-0 3-(4-methylphenyl)prop-2-enyl acetate 
• 134539-87-0 1-methyl-4-(3-phenyl-1-propen-1-yl)benzene 
• 134539-86-9 1-methyl-4-(3-phenyl-2-propen-1-yl)benzene 
• 99686-39-2 (E)-2-bromo-3-phenylprop-2-enal 

Relevant articles and documents

Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes

A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.