134539-86-9

Basic information

• Product Name: Benzene, 1-methyl-4-[(2E)-3-phenyl-2-propenyl]-
• CAS NO: 134539-86-9
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 134539-86-9.mol
• Article Data: 59

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(2E)-3-phenyl-2-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(2E)-3-phenyl-2-propenyl]-(134539-86-9)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(2E)-3-phenyl-2-propenyl]-(134539-86-9)

Safety Data

• Hazardous Substances Data: 134539-86-9(Hazardous Substances Data)

Upstream product

• 103-54-8 cinnamyl acetate 
• 5142-75-6 tri(p-tolyl)bismuth 
• 4224-87-7 4-methyl-chalcone 
• 37464-41-8 phenyl 3-phenyl-allyl ether 
• 5720-05-8 4-methylphenylboronic acid 
• 34862-98-1 C₁₆H₁₅Br 
• 122-00-9 para-methylacetophenone 
• 166824-01-7 α-phenyl p-methylcinnamyl alcohol 
• 87802-71-9 (E)-methyl cinnamyl carbonate 
• 108-88-3 toluene 
• 160879-62-9 methyl 1-phenylprop-2-enyl carbonate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 21040-45-9 Cinnamyl acetate 

Downstream Products

• 102759-89-7 1-Phenyl-3-p-tolyl-1-(N,N'-dicarbethoxy-hydrazino)-2-propen 
• 134539-88-1 2-((E)-1-Phenyl-3-p-tolyl-allyl)-2-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-malononitrile 
• 134539-89-2 2-((E)-3-Phenyl-1-p-tolyl-allyl)-2-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-malononitrile 
• 113325-60-3 1-Phenyl-3-p-tolyl-1-(N,N'-dicarbethoxy-hydrazino)-propan 
• 131516-71-7 1-Brom-1-phenyl-3-p-tolyl-propan 
• 4224-87-7 4-methyl-chalcone 
• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 1220346-18-8 (E)-4-methylbenzaldehyde O-(E)-3-phenyl-1-p-tolylallyl oxime 
• 1220346-16-6 (E)-4-methylbenzaldehyde O-(E)-1-phenyl-3-p-tolylallyl oxime 
• 1352733-26-6 (E)-5-(4-methylstyryl)-1-phenyl-1H-tetrazole 
• 1352733-07-3 (E)-5-styryl-1-(p-tolyl)-1Htetrazole 
• 191542-57-1 ethyl 3-oxo-2-((E)-1,3-diphenyl-2-propenyl)butanoate 
• 1431318-01-2 3-benzyl-7-methyl-1,2-diphenylnaphthalene 
• 6876-68-2 N-(4-methylphenyl)-3-phenyl-2-propenamide 

Relevant articles and documents

Allylation of arenes catalysed by thiolate-bridged diruthenium complexes

In the presence of catalytic amounts of cationic thiolate-bridged diruthenium complexes, arenes react with allylic alcohols to afford the corresponding allylated aromatic products in high yields.

Catalyst-free suzuki-type coupling of allylic bromides with arylboronic acids

The coupling of arylboronic acids with electron-rich allylic bromides is accomplished in the absence of any transition-metal catalyst through conventional heating. The reaction is completely regioselective, affording only the α-coupled product, and can be carried out under mild aerobic conditions in an organic solvent; the presence of a base is required. Copyright

An efficient 1,3-allylic carbonyl transposition of chalcones

A very simple, convenient, and efficient procedure is reported for the 1,3-allylic carbonyl transposition of chalcones. The transposition can be achieved by reduction of chalcones to 1,3-diarylpropan-1-ols and dehydration of the latter to give 1,3-diarylpropenes followed by benzylic/allylic oxidation.

Nickel-catalyzed cross-electrophile coupling of aryl chlorides with allylic alcohols

Nickel-catalyzed cross-electrophile coupling of aryl chlorides with allylic alcohols proceeds readily under mild conditions in the presence of zinc powder and MgCl2to produce allylarenes in 25-92% yields. The reaction shows high regioselectivit

Reciprocal-Activation Strategy for Allylic Sulfination with Unactivated Allylic Alcohols

A reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols was developed. In this reaction, the hydrogen bond interaction between allylic alcohols and sulfinic acids allowed for reciprocal activation, which enabled a dehydrative cross-coupling process to occur under mild reaction conditions. This reaction worked in an environmentally friendly manner, yielding water as the only byproduct. A variety of allylic sulfones could be obtained in good to excellent yields with wide functional group tolerance. In gram scale reactions, allylic sulfones could be conveniently isolated in high yield by filtration.