145259-80-9

Basic information

• Product Name: (3R,4R,4aR,10aR)-2-Benzyloxy-6,6,8,8-tetraisopropyl-4-methoxy-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol
• CAS NO: 145259-80-9
• Molecular Weight: 526.818
• Mol File: 145259-80-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4R,4aR,10aR)-2-Benzyloxy-6,6,8,8-tetraisopropyl-4-methoxy-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,4aR,10aR)-2-Benzyloxy-6,6,8,8-tetraisopropyl-4-methoxy-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol(145259-80-9)
• EPA Substance Registry System: (3R,4R,4aR,10aR)-2-Benzyloxy-6,6,8,8-tetraisopropyl-4-methoxy-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol(145259-80-9)

Safety Data

• Hazardous Substances Data: 145259-80-9(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 3370-81-8 3-O-methyl-D-glucopyranose 
• 30694-99-6 Benzyl 3-O-methyl-D-glucopyranoside 
• 69304-37-6 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 

Downstream Products

• 143836-18-4 (2S,4aR,7R,8S,8aR)-7-Benzoyloxy-6-benzyloxy-8-methoxy-2-methyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid methyl ester 
• 145259-88-7 Benzoic acid (3R,4R,4aR,10aR)-2-benzyloxy-6,6,8,8-tetraisopropyl-4-methoxy-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-yl ester 

Relevant articles and documents

Convenient synthesis of 4,6-O-pyruvate acetal containing glycosides via tetraisopropyldisiloxanediyl protected sugars

Treatment of alkyl D-glycopyranosides and alkyl or phenyl 1-thio-β-D-glycopyranosides 1 with 1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane gave the corresponding 4,6-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl) protected glycosides 2 which were subsequen