1453494-34-2

Basic information

• Product Name: C₁₂H₁₃NO₃S
• CAS NO: 1453494-34-2
• Molecular Weight: 251.306
• Mol File: 1453494-34-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₃NO₃S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₃NO₃S(1453494-34-2)
• EPA Substance Registry System: C₁₂H₁₃NO₃S(1453494-34-2)

Safety Data

• Hazardous Substances Data: 1453494-34-2(Hazardous Substances Data)

Upstream product

• 88036-12-8 3-(Phenylsulfonyl)-2-cyclohexen-1-one 

Downstream Products

• 26815-49-6 1-amino-3-phenylsulfonylbenzene 

Relevant articles and documents

Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines

Homogeneous Pd catalysts have been identified for the conversion of cyclohexenone and tetralone O-pivaloyl oximes to the corresponding primary anilines and 1-aminonaphthalenes. This method is inspired by the Semmler-Wolff reaction, a classic method that exhibits limited synthetic utility owing to its forcing conditions, narrow scope, and low product yields. The oxime N-O bond undergoes oxidative addition to Pd0(PCy3)2, and the product of this step has been characterized by X-ray crystallography and shown to undergo dehydrogenation to afford the aniline product.