88036-12-8

Basic information

• Product Name: 2-Cyclohexen-1-one, 3-(phenylsulfonyl)-
• CAS NO: 88036-12-8
• Molecular Formula: C12H12O3S
• Molecular Weight: 236.291
• Mol File: 88036-12-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 3-(phenylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 3-(phenylsulfonyl)-(88036-12-8)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 3-(phenylsulfonyl)-(88036-12-8)

Safety Data

• Hazardous Substances Data: 88036-12-8(Hazardous Substances Data)

Upstream product

• 75717-39-4 3-(phenylsulfanyl)cyclohex-2-en-1-one 
• 108-98-5 thiophenol 
• 504-02-9 1,3-cylohexanedione 
• 2525-42-0 phenylsulfonylpropa-1,2-diene 
• 94404-09-8 (4-Benzenesulfonyl-5-methylene-cyclohex-1-enyloxy)-trimethyl-silane 
• 5682-75-7 3-chloro-2-cyclohexenone 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 123488-02-8 (S)-Methoxy-phenyl-acetic acid (S)-3-benzenesulfonyl-cyclohex-2-enyl ester 
• 123488-43-7 (S)-Methoxy-phenyl-acetic acid (R)-3-benzenesulfonyl-cyclohex-2-enyl ester 
• 1453494-34-2 C₁₂H₁₃NO₃S 
• 26815-49-6 1-amino-3-phenylsulfonylbenzene 
• 65825-82-3 3-(Phenylsulfonyl)cyclohex-2-en-1-ol 

Relevant articles and documents

A Stereocontrolled Cyclopentenone Synthesis via Cycloaddition

γ-Alkoxy-α,β-unsaturated sulfones are readily available in both racemic and scalemic form, the latter either by asymmetric induction from achiral building block or from readily available scalemic starting materials.These electron deficient olefins serve as excellent substrates for cycloaddition involving the intermediacy of trimethylenemethane-palladium complexes.The highly diastereoselective methylenecyclopentannulation provides a versatile cycloadduct that allows very simple conversion to cyclopentenones and cyclopentadienes and the synthetic equivalent ofaddition to cycloalkanones and alkynones, two classes of substrate that either frequently give low yields or totally fail in palladium-catalyzed cycloadditions from 2-(acetoxymethyl)-3-(trimethylsilyl)prop-1-ene.

Reagent Design and Study of Allene as a Promising Class of Reagents (Synthons) for Cycloaddition. The Site Selective and Regioselective Diels-Alder Reactions of (Phenylsulfonyl)propadiene and Alkylation of the Adducts.

The cycloaddtion reaction of title compound 1 with 1,3-dienes and troponoid compounds has been investigated.The reactions with dienes 2-8 proceeded in remarkable site selective and regioselective manners to give the Diels-Alder adducts 9-15 possessing an